Alkaline metal and alkaline earth metal salts of di(1H-tetrazol-5-yl)methanone (DTO): energetic catalysts for ammonium perchlorate decomposition

Abstract

To explore novel coordination complexes for promising energetic materials, alkaline metal (Na+ (1), Na+ (2), K+ (3), and Rb+ (4)) and alkaline earth metal (Mg2+ (5), Ca2+ (6), and Sr2+...

Construction of High-Performance Energetic MOFs: C4N8O42– and C3N4O42– with Their Derivatives, Compared with Their Energetic Salts

“…A suitable metal ion coordinated with energetic anions through coordination bonds can enormously improve the density, decomposition temperature, and thermal stability. ,− Many metal ions combined with fragrant rings have been used to build several beautiful-structure E -MOFs (Figure 12 ). EMs in this class are famous for their high detonation velocities, pressure, and sensitivity to mechanical stimulation. − …”

Cupric coordination compounds with multiple anions: a promising strategy for the regulation of energetic materials

“…Several strategies have been applied to develop new energetic compounds, such as constructing nitrogen-rich energetic cocrystals, designing, and synthesizing novel nitrogen-rich energetic compounds, forming nitrogen-rich energetic salts and energetic coordination complexes (ECCs). [5][6][7][8][9] Moreover, owing to ECCs usually consisting of three moieties (metal cations, energy-storage ligands, and anions), ECCs can easily adjust their performance by changing the three moieties. 5 Therefore, many energetic coordination complexes have been prepared with excellent properties that can be used as catalysts to promote ammonium perchlorate decomposition, as primary explosives, or as promoters for ionic liquid hypergolic ignition.…”

Polymeric Carbon Nitride/Iron Oxide Composites: A Novel Class of Catalysts with Reduced Metal Content for Ammonium Perchlorate Thermal Decomposition

“…The emergence of new catalyst systems that can adequately serve the quest for future energetic materials with low toxicity, high performance, easy preparation, and less pollution has become the need of the hour. , In the present work, we have adopted a cost-effective, facile, and scalable hydrothermal-assisted synthesis route requiring a minimal number of chemicals (Figure ). This can be the first step toward the construction of gCN/α-Fe 2 O 3 heterojunctions for the thermal decomposition studies of AP.…”