Alkoxycarbonylation of Unsaturated Substrates of Plant Origin in the Presence of Palladium Catalysts as a Route to Synthesize Ester Products

Sevostyanova, N. T.; Batashev, S. A.

doi:10.1134/s2070050423040104

Catal. Ind.

2023

DOI: 10.1134/s2070050423040104

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Alkoxycarbonylation of Unsaturated Substrates of Plant Origin in the Presence of Palladium Catalysts as a Route to Synthesize Ester Products

N. T. Sevostyanova,

S. A. Batashev

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2024

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Cited by 2 publications

References 99 publications

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Strong Acid‐Free Homogeneous Catalytic Systems for the Ester Products Synthesis by Alkenes Alkoxycarbonylation: Recent Advances

Sevostyanova,

Batashev

2024

Eur J Org Chem

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Alkoxycarbonylation represents a method for the ester products synthesis from available reagents – unsaturated compounds, alcohols, and CO. The beginning of research on this reaction was laid in W. Reppe’ works in 1953. In early works, halides and carbonyls of Co, Ni, Rh, and Ir were used as catalysts, and alkoxycarbonylation was often complicated by the unsaturated compounds hydroformylation or alcohol carbonylation. In recent decades, in the presence of the most active and selective Pd‐phosphine systems with strong protonic acids, the products are typically only isomeric esters, which corresponds to the creating waste‐free production principles. At present, a large‐capacity synthesis process for methyl methacrylate, dubbed Alpha, is in operation, with the initial stage being ethylene methoxycarbonylation. In light of these developments, there is a growing interest among chemists and technologists in alkenes alkoxycarbonylation. The use of strong protonic acids as co‐catalysts is essential for the formation of active catalytic complexes. However, these acids are highly corrosive and can cause the alkenes isomerisation. This review is devoted to the analysis of acid‐free homogeneous Pd‐, Ru‐, Co‐, and Ni‐catalysts employed in alkenes alkoxycarbonylation over the past 15 years. As a result, polymers, monomers and other valuable linear and branched esters were obtained.

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Strong Acid‐Free Homogeneous Catalytic Systems for the Ester Products Synthesis by Alkenes Alkoxycarbonylation: Recent Advances

Sevostyanova,

Batashev

2024

Eur J Org Chem

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Investigation of the Dependence of the Rate of Cyclohexene Alkoxycarbonylation with Cyclohexanol and CO on the p-Toluenesulfonic Acid Monohydrate Concentration and Temperature

Sevostyanova,

Batashev

2024

Pet. Chem.

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Alkoxycarbonylation of Unsaturated Substrates of Plant Origin in the Presence of Palladium Catalysts as a Route to Synthesize Ester Products

Cited by 2 publications

References 99 publications

Strong Acid‐Free Homogeneous Catalytic Systems for the Ester Products Synthesis by Alkenes Alkoxycarbonylation: Recent Advances

Strong Acid‐Free Homogeneous Catalytic Systems for the Ester Products Synthesis by Alkenes Alkoxycarbonylation: Recent Advances

Investigation of the Dependence of the Rate of Cyclohexene Alkoxycarbonylation with Cyclohexanol and CO on the p-Toluenesulfonic Acid Monohydrate Concentration and Temperature

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