Alkylpolyglycoside – Eigenschaften und Anwendungen einer neuen Tensidklasse

Rybinski, Wolfgang von; Hill, Karlheinz

doi:10.1002/(sici)1521-3757(19980518)110:10<1394::aid-ange1394>3.0.co;2-t

Cited by 43 publications

(5 citation statements)

References 73 publications

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“…Both, at present, are of little significance as six-carbon building blocks, despite a surprisingly effective route to cyclo-pentanoid products [101] which is surmised to have industrial potential (Scheme 6). An established, non-food application of D-glucose are the alkyl polyglucosides ('APGs'), which combine high performance as non-ionic surfactants with non-toxicity, low-skin irritation, and biodegradability [102]. They are technically produced − on an estimated 50 000-t scale worldwide presently − either through acid-induced glycosidation of glucose with a long chain fat alcohol or by transglycosylation of a shortchain alkyl glucoside with the appropriate long-chain alkanol.…”

Section: Non-food Valorisation Of Glucosementioning

confidence: 99%

Carbohydrates as green raw materials for the chemical industry

Lichtenthaler

Peters

2004

Comptes Rendus. Chimie

345

128

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In view of the impending transition of chemical industry from depleting fossil raw materials to renewable feedstocks − the end of cheap oil is predicted for 2040 at the latest − this account gives an overview on chemically transforming low-molecular weight carbohydrates into products with versatile industrial application profiles and the potential to replace those presently derived from petrochemical sources.

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Section: Non-food Valorisation Of Glucosementioning

confidence: 99%

Carbohydrates as green raw materials for the chemical industry

Lichtenthaler

Peters

2004

Comptes Rendus. Chimie

345

128

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“…Recently, Villandier and Corma reported the one‐pot catalytic conversion of cellulose into long‐chain alkyl glycosides,117 known for their excellent surfactant properties, low toxicity, and good biodegradability 118. The method is based on the hydrolysis of α‐cellulose over Amberlyst 15 DRY in BMImCl, in the presence of a small amount of water.…”

Section: One‐pot Catalytic Transformation Into Alkyl Glycosidesmentioning

confidence: 99%

Recent Advances in the Catalytic Conversion of Cellulose

et al. 2010

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“…New syntheses with oils and fats as well as carbohydrates [42] as renewable raw materials for the chemical industry were quite recently reviewed [33]. Alkyl polyglucosides are a good example; they are produced as skin-compatible, environmentally benign tensides on a scale of 70 000 t/a [43].…”

Section: Renewable Feedstocks For the Chemical Industrymentioning

confidence: 99%

Concepts on the contribution of chemistry to a sustainable development. Renewable raw materials

Metzger

Eissen²

2004

Comptes Rendus. Chimie

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The principles of the Rio Conference (1992) and Agenda 21 address the pressing problems of today and also aim at preparing the world for the challenges of this century. The conservation and management of resources for development are the main foci of interest, to which chemistry will have to make a considerable contribution. Since base chemicals are produced in large quantities and important product lines are synthesized from them, their resource-saving production is especially important for a sustainable development. New processes based on renewable feedstocks are significant here. Most products that are obtained from renewable raw materials may, at present, not be able to compete with the products of the petrochemical industry, but this will change as oil becomes scarcer and oil prices rise. The design of chemical products should make sustainable processing and recycling possible, and should prevent their bioaccumulation. Methods and criteria to assess their contribution to a sustainable development are necessary. The time necessary to introduce the new more sustainable processes and products has to be diminished by linking their development with operational innovation management and with efficient environmental-political control procedures.

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Alkylpolyglycoside – Eigenschaften und Anwendungen einer neuen Tensidklasse

Cited by 43 publications

References 73 publications

Carbohydrates as green raw materials for the chemical industry

Carbohydrates as green raw materials for the chemical industry

Recent Advances in the Catalytic Conversion of Cellulose

Concepts on the contribution of chemistry to a sustainable development. Renewable raw materials

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