The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10. 1002/adfm.201801958. tives to replace complex and bulky optical elements. This unique ability is due to strong modifications of the local density of optical states occurring in sub-micrometric objects made of materials featuring high dielectric constant and sufficiently small absorption losses.Most studies over the last years have mainly addressed silicon- [4][5][6][7][8][9][10] and germanium-based [11][12][13][14] Mie resonators, demonstrating that they could outperform their metallic counterpart supporting localized plasmonic resonances. However, the large absorption of group IV semiconductor compounds at short wavelengths induces strong optical losses, limiting their potential applicability as efficient devices especially at blue and near-UV frequencies [15,16] (e.g. at 450 nm: n Si = 4.5, k Si = 0.13; n Ge = 4.0, k Ge = 2.24). Furthermore, with a few exception based on colloids [4,17,18] and solid state dewetting, [13,[19][20][21][22][23] typical nanofabrication methods of Si(Ge)-based Mie resonators rely on top-down technologies that are not easy to scale-up at affordable prices.TiO 2 -based optical devices are an interesting alternative to Si, since Titania has a relatively high refractive index and is fully transparent up to UV frequencies [24,25] (e.g.: at 450 nm: n TiO2 = 2.55, k TiO2 = 1.2 × 10 −5 ; at 370 nm: n TiO2 = 2.83, k TiO2 = 1 × 10 −3 ) rendering it, for instance, a strategic material to manipulate the light emitted by conventional GaN-based blue LEDs (at about 450 nm). TiO 2 can be prepared by high-throughput chemical processes, which is a prerequisite for applications requiring large surface systems. It also has many other advantages over Si and metals that are its high chemical, mechanical, and thermal stability, nontoxicity, and relative natural abundance.To date, several groups have studied the properties of Titania particles as dielectric resonators prepared using conventional top-down microfabrication technologies [26][27][28][29][30] or soft-nanoimprint lithography. [31,32] They all confirmed that electromagnetic resonances could be generated within these metal oxide objects. However, the limited exploitation of this material is mainly due to the difficulty in applying conventional top-down fabrication methods to TiO 2 . Additionally, such approaches do not allow the preparation of spherical resonators, [33] which may be interesting for many applications with effective metamaterials, such as beam steering and back-scattering-free optics, [11,[34][35][36][37][38][39][40][41][42][43][44][45]