The Kimberley Process Certification Scheme (KPCS) was established in 2000 as a means of controlling the flow of conflict diamonds, mostly, from the African continent. In 2013, the KPCS imposed an embargo on diamonds from the Central African Republic (CAR). Since then the embargo has been lifted in certain prefectures of the country, however, smuggling is suspected from non-compliant areas.
Three parcels of diamonds suspected to have mining origins in the CAR, were analysed. These diamonds were investigated for their morphological and chemical characteristics, to establish a diamond fingerprint and to determine if these diamonds had the same fingerprint as previously analysed diamonds from CAR or the Democratic Republic of the Congo (DRC). The analyses of these diamonds were included in the already established diamond database of rough diamonds from the African continent.
The morphological characteristics identified included the mass (ct), colour, surface coatings, dominant, secondary and tertiary form, shape, breakage, inclusions, abrasion and surface features that are specific to octahedral, dodecahedral and cubic shapes. The morphological characteristics determined from the diamonds revealed that morphology alone cannot be used as a discriminatory method for diamond fingerprinting.
Fourier transform infrared spectroscopy (FTIR) identified the nitrogen concentration and aggregation state of that N. This allowed for the typing of the diamonds as Type I (containing N) and Type II (containing no measureable N). The concentration of N in the three parcels is less than 600 ppm. Further classification of Type I diamonds was performed according to the N aggregation state as single, double or four-fold. The vast majority of diamonds show a combination of nitrogen aggregation states while few were classified as Type II. Fourier transform IR showed no discernible trends between the current study and the established database.
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used as a means of determining the trace element concentrations of
69
Ga,
88
Sr,
89
Y,
90
Zr,
93
Nb,
133
Cs,
137
Ba,
139
La,
140
Ce,
141
Pr,
146
Nd,
147
Sm,
153
Eu,
157
Gd,
159
Tb,
163
Dy,
165
Ho,
166
Er,
169
Tm,
172
Yb,
175
Lu,
178
Hf,
181
Ta,
232
Th and
238
U. Laser ablation ICP-MS determined that not all elements produce statistically viable data, however, the data could still be used to discern trace element d...