2021
DOI: 10.1016/j.poly.2021.115357
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Allylnickel(II) complexes of bulky 5-substituted-2-iminopyrrolyl ligands

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Cited by 7 publications
(12 citation statements)
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“…Characterization by 1 H NMR spectroscopy allowed the determination of the branching degree, i.e. the number of branches per 1000 carbon atoms, , with all of the polyethylene products revealing high values of branching, in the range 100–115 branches/1000 C, being classified as hyperbranched PEs, values similar to those previously reported by our group for phenyl Ni­(II) triphenylphosphine complexes …”
Section: Resultssupporting
confidence: 90%
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“…Characterization by 1 H NMR spectroscopy allowed the determination of the branching degree, i.e. the number of branches per 1000 carbon atoms, , with all of the polyethylene products revealing high values of branching, in the range 100–115 branches/1000 C, being classified as hyperbranched PEs, values similar to those previously reported by our group for phenyl Ni­(II) triphenylphosphine complexes …”
Section: Resultssupporting
confidence: 90%
“…On the other hand, the electron-withdrawing 5-[3,5-(CF 3 ) 2 C 6 H 3 ] substituent in complexes 1a and 2a increases the chain transfer rate, causing a decrease in the molecular weight of the obtained polymers. These observations are analogous to those for phenyl Ni­(II) triphenylphosphine complexes previously reported by our group …”
Section: Resultssupporting
confidence: 80%
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“…Our group has been engaged in the coordination chemistry of 5-substituted-2-iminopyrrolyl ligands and its multiple applications. Using our previous experience with this ligand framework, in particular with iron and cobalt complexes applied to alkene and aldehyde hydroboration (Chart , VIII ), this work reports the synthesis and characterization of an alkyl-manganese­(II) complex bearing a 5-aryl-2-iminopyrrolyl ligand (Chart , IX ) capable of catalyzing the atom-economical hydrosilylative reduction of aldehydes and ketones to the respective alcohols, utilizing very mild reaction conditions.…”
Section: Introductionmentioning
confidence: 99%