Abstract:By combination of high trapping radical efficiency of thioketone with resonance of allylic radicals, a novel mediated agent, 1,3,3‐triphenylprop‐2‐ene‐1‐thione (TPPT) is successfully synthesized. The results of studying TPPT‐mediated radical polymerization of styrene (St) respectively at 70 °C and 100 °C reveal that at 70 °C, the monomer conversion is very low (less than 5%), the molecular weights do not change obviously with the monomer conversion, and their molecular weights are also low. However, the polyme… Show more
TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.
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