In the present paper, we give some characterizations by considering * -Ricci soliton as a Kenmotsu metric. We prove that if a Kenmotsu manifold represents an almost * -Ricci soliton with the potential vector field V is a Jacobi along the Reeb vector field, then it is a steady * -Ricci soliton. Next, we show that a Kenmotsu matric endowed an almost * -Ricci soliton is Einstein metric if it is η-Einstein or the potential vector field V is collinear to the Reeb vector field or V is an infinitesimal contact transformation.