“…Aluminum nitride is a semiconductor of the III-V semiconductor group, with an hexagonal wurtzite crystalline structure (Penza et al, 1995;Xu et al, 2001), lattice constants of a = 0.3110 nm e c =0.4980 nm (Xu et al, 2001), and is characterized by a broad direct energy gap (6.2 eV) (Cheng et al, 2003;Hirata et al, 2007;Penza et al, 1995), chemical stability (Cheng et al, 2003;Penza et al, 1995), high thermal conductivity (3.2 W/mK) (Cheng et al, 2003), low thermal expansion coefficient (4.5 ppm/°C) (Ruffner et al, 1999), high breakdown voltage (Hirata et al, 2007;Xu et al, 2001), high acoustic speed (Cheng et al, 2003;Xu et al, 2001), high refractive index (n = 2.1) (Penza et al, 1995), high electrical resistivity (10 11 -10 14 cm) (Ruffner et al, 1999) and, above all, good piezoelectric response (Cheng et al, 2003;Hirata et al, 2007;Penza et al, 1995;Ruffner et al, 1999;Xu et al, 2001) (piezoelectric coefficient of 5.4 pm/V) (Ruffner et al, 1999). Piezoelectric behaviour of AlN strongly depends on its crystallographic orientation (Cheng et al, 2003) and, in particular, films grown in the [002] orientation are preferred as the highest www.intechopen.com…”