The recently observed α-decay chain 108 Xe → 104 Te → 100 Sn [K. Auranen et al., Phys. Rev. Lett. 121, 182501 (2018)] could provide valuable information on the α clustering in even-even nuclei slightly above the major shells Z = 50 and N = 50. In this work, this α-decay chain is studied theoretically within the framework of the density-dependent cluster model plus the twopotential approach. We calculate the α-decay half-lives of 104 Te and 108 Xe and study in detail their dependence on the Q value and the density-profile parameters of the core nucleus. Various physical properties of 104 Te, the heaviest nucleus with a doubly magic self-conjugate core + α, are calculated, with two different assumptions on the renormalization factor of the double-folding potential, which could be a useful reference for future experimental studies.