1968
DOI: 10.1021/ac60259a029
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Alternating current polarography and irreversible processes

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1971
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Cited by 57 publications
(26 citation statements)
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“…The aforemen- tioned phenomena indicate that an piperidine aminoxyl radical is reducible on the electrode, and that a proton takes part in the electrode process. The results are also characteristic of an electrode reaction followed by a chemical reaction, as proposed by theoretical studies [36][37][38]. Piperidine aminoxyl radicals undergo a single electron reduction first on the electrode followed by protonation to generate the corresponding hydroxylamine (Scheme 6).…”
Section: Reductionmentioning
confidence: 70%
“…The aforemen- tioned phenomena indicate that an piperidine aminoxyl radical is reducible on the electrode, and that a proton takes part in the electrode process. The results are also characteristic of an electrode reaction followed by a chemical reaction, as proposed by theoretical studies [36][37][38]. Piperidine aminoxyl radicals undergo a single electron reduction first on the electrode followed by protonation to generate the corresponding hydroxylamine (Scheme 6).…”
Section: Reductionmentioning
confidence: 70%
“…The concentration ratio of the PdL i and PdL i + 1 complexes, one can use ratio (2) of the peak currents in the alternating current polarograms [4,6].…”
Section: Doi: 101134/s1070363208020229mentioning
confidence: 99%
“…[1], both equations being identical with the set of parameters given. Some typical data to show the comparison of rapid and conventional d-c polarograms for irreversible electrode processes are given in Table I. For irreversible a-c electrode processes, Es is more negative than E1/2, and as for d-c polarography, the wave shape is independent of ks (19). The difference between Es and E1/2 depends principally on ks, n, and a and Es is also related to drop time in a similar fashion to E1/2 (19).…”
Section: Vol 118 No 10mentioning
confidence: 99%
“…Some typical data to show the comparison of rapid and conventional d-c polarograms for irreversible electrode processes are given in Table I. For irreversible a-c electrode processes, Es is more negative than E1/2, and as for d-c polarography, the wave shape is independent of ks (19). The difference between Es and E1/2 depends principally on ks, n, and a and Es is also related to drop time in a similar fashion to E1/2 (19). Hence with rapid a-c polarography, the behavior on decreasing the drop time gives rise to a more negative Es value, the wave shape, however, remains essentially unaltered.…”
Section: Vol 118 No 10mentioning
confidence: 99%