The basic structure of high-field EL is an alternating-current electroluminescent (ACEL) device, where the electrons in the phosphor or injected by the electrode are accelerated in the crystal and collide with the luminescent center to excite or ionize under the applied electric field, and emit radio light when electrons return to the ground state. [11,12] Compared to the traditional LED, the ACEL device has attracted widespread concerns due to its low power consumption, long service life, and excellent mechanical stability, however, the high frequency and unavoidable high driving voltage required for light-emitting limits the wide application in smart wearable field. Meanwhile, with the rapid development of science and technology, electronic devices have shown a trend of miniaturization, low power consumption, and multi-function, thus it is urgent to find a low carbon, environmentally friendly, and clean energy to get rid of the dependence on traditional power sources. Pioneered by Wang and co-workers, nanogenerators based on the coupling of the triboelectrification and electrostatic induction have been developed in the last few years, [13][14][15] ushering a new era of environmental energy collection and utilization. Unlike traditional chemical batteries, which have a limited lifespan and need to be replaced or recharged frequently. [16][17][18] The TENG have shown unprecedented output performance and advantages in harvest randomly distributed or irregular mechanical energy from the environment into electrical energy,
Low frequency, portable power source is one of the key challenges for applications of wearable alternating-current electroluminescent (ACEL) device because it typically requiresa working frequency above 500 Hz. Here, an extremely low frequency self-powered ACEL system is proposed, which consists of a vertical contact-separation triboelectric nanogenerator and a self-made flexible ACEL device. It achieves directly-driven electroluminescence phenomenon in real-time by triboelectrification and works completely self-powered through converting kinetic energy of human body into electricity. The working frequency has fallen from 500 to 1 Hz, i.e., the real frequency needed for electroluminescence has dropped 500 times, which is due to the favorable low-frequency high-voltage advantages of the triboelectric nanogenerator. It delivers a stabilized open-circuit voltage of 160 V and a short-circuit current of 6 µA for applied force of 0.1 N. Meanwhile, a strong blueshift is also observed experimentally with the change of working frequency. Furthermore, a self-powered medical protective gown is demonstrated that is real-time monitoring both the temperature and humidity. This work breaking the bottleneck of high-frequency driving, demonstrates the great potential of self-powered ACEL systems in wearable electronics and medical health.