Aluminium as anode in primary alkaline batteries. Influence of additives on the corrosion and anodic behaviour of 2S aluminium in alkaline citrate solution

Sarangapani, K.B.; Balaramachandran, V.; Kapali, V.; Iyer, S. Venkatakrishna; Potdar, M. G.; Rajagopalan, K. S.

doi:10.1007/bf00610812

Cited by 26 publications

(6 citation statements)

References 3 publications

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“…In the efforts to decrease the corrosion rate of aluminum, it was found that the incorporation of inhibitive and complexing substances is helpful. [26][27][28][29] Daufin, et al, found that calcium ions, in combination with tartrate and citric acid (C 6 H 8 O 7 ), showed the highest inhibition efficiency, 28 but the reaction mechanism of the additives is still unclear. In the present work, the inhibition mechanism of calcium tartrate on pure aluminum in an alkaline solution was studied systematically.…”

Section: Introductionmentioning

confidence: 97%

Inhibition Effect of Calcium Tartrate on the Corrosion of Pure Aluminum in an Alkaline Solution

Shao¹,

Wang²,

Zhang³

et al. 2001

CORROSION

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The corrosion behavior of aluminum in 1 M potassium hydroxide (KOH) solution with and without calcium tartrate was investigated by means of weight loss measurement, open-circuit potential measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy. Experimental results showed that the corrosion of aluminum was inhibited by the addition of calcium tartrate. At high calcium tartrate concentrations, the anodic and cathodic processes were greatly inhibited. At its low concentration, the effect of the inhibitor on the former was much stronger than that on the latter. This might have been caused by the selective adsorption of the inhibitor on anodic active sites.

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Section: Introductionmentioning

confidence: 97%

Inhibition Effect of Calcium Tartrate on the Corrosion of Pure Aluminum in an Alkaline Solution

Shao¹,

Wang²,

Zhang³

et al. 2001

CORROSION

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“…The open circuit potential of this alloy is À1.803 V (vs. SCE) measured in seawater. [18][19][20][21] Recently, our group 22 has studied the electrochemical performance of Mg-8Li-1Y electrode in 0.7 mol L À1 NaCl solutions containing different concentrations of Na 2 SnO 3 . 17 They found that this Mg-Li alloy exhibited higher anodic efficiencies (81%) corresponding to the high current density (8.6 mA cm À2 ).…”

Section: Introductionmentioning

confidence: 99%

“…The oxides of gallium, indium, calcium and zinc, and stannates as well as citrates, were found to be effective electrolyte additives for inhibiting corrosion and/or boosting discharge current density. [18][19][20][21] Recently, our group 22 has studied the electrochemical performance of Mg-8Li-1Y electrode in 0.7 mol L À1 NaCl solutions containing different concentrations of Na 2 SnO 3 . It was found that the peak power density of the semi-fuel cell with Mg-8Li-1Y alloy as the anode in 0.7 mol L À1 NaCl solution with 0.3 mmol L À1 Na 2 SnO 3 (112 mW cm À2 ) is higher than that in 0.7 mol L À1 NaCl solution without Na 2 SnO 3 (83 mW cm À2 ).…”

Section: Introductionmentioning

confidence: 99%

The effects of sodium fluoride as the electrolyte additive on the electrochemical performances of magnesium–8lithium–0.5zinc electrode in sodium chloride solution

Tang

et al. 2014

RSC Adv.

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The electrochemical performance of Mg-8Li-0.5Zn electrode in 0.7 mol L À1 NaCl solution with different concentrations of NaF (0.0, 0.2, 0.5, 0.8, 1.0, 1.2 and 1.5 mmol L À1 ) was investigated by means of potentiodynamic polarization, potentiostatic current-time curves, electrochemical impedance spectroscopy, scanning electron microscopy and utilization efficiencies. The findings indicate that Mg-8Li-0.5Zn electrode in 0.7 mol L À1 NaCl solution with 1.0 mmol L À1 NaF has a higher discharge current density than that in 0.7 mol L À1 NaCl solution with the other concentrations of NaF that were investigated. The addition of 1.0 mmol L À1 NaF to the NaCl electrolyte solution loosens the product film and the oxidation products on the alloy surfaces of the electrode, which produces deeper and larger channels, as observed by the SEM investigation, compared with those in 0.7 mol L À1 NaCl solution without any NaF. The addition of 1.0 mmol L À1 NaF in 0.7 mol L À1 NaCl solution improves the continuous discharging utilization efficiency of Mg-8Li-0.5Zn electrode by more than 18.80%, and enhances the interval discharge utilization efficiency of Mg-8Li-0.5Zn electrode by more than 27.90%.

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“…Nevertheless, quite a large number of organic compounds inhibit corrosion in dilute solutions but eventually fail at higher concentrations. Carbonic acids (Horiguchi et al , 1966), aliphatic and aromatic amines (Sarangapani et al , 1984), diketones (Horiguchi et al , 1966), phenolic compounds (Subramanyan et al , 1971) alkaloids (Subramanyan and Ramakrishnaiah, 1971) alizarin derivatives were tried as inhibitors.…”

Section: Introductionmentioning

confidence: 99%

Novel polymeric inhibitor for corrosion of 57S aluminium in 2M NaOH solutions

Elango

Periasamy

Paramasivam

et al. 2010

Anti-Corrosion Methods and Materials

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PurposeThe purpose of this paper is to show how to develop inhibition 57S aluminium in 2M NaOH solution.Design/methodology/approachThe approach is used to measure gravimetric and polarization measurements.FindingsThe results of the paper clearly reveal that the 0.2 M ZnO with 700 ppm polyaniline in N‐methyl‐2‐pyrrolidone solution is found to offer inhibition up to 71.2 per cent.Originality/valueThe paper deals with the development of newer inhibitor based on polyaniline. Gravimetric and galvanostatic methods were employed to evaluate inhibition efficiency.

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Aluminium as anode in primary alkaline batteries. Influence of additives on the corrosion and anodic behaviour of 2S aluminium in alkaline citrate solution

Cited by 26 publications

References 3 publications

Inhibition Effect of Calcium Tartrate on the Corrosion of Pure Aluminum in an Alkaline Solution

Inhibition Effect of Calcium Tartrate on the Corrosion of Pure Aluminum in an Alkaline Solution

The effects of sodium fluoride as the electrolyte additive on the electrochemical performances of magnesium–8lithium–0.5zinc electrode in sodium chloride solution

Novel polymeric inhibitor for corrosion of 57S aluminium in 2M NaOH solutions

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