Organic solar cells (OSCs) have fascinated society for their environmental friendliness, but the asymmetric mobility of the organic absorber continues to be identified as the primary issue impeding efficiency (η). The effort has been explored through the attributes of different fullerene derivatives based on absorber thickness that suggest new physical insights into the roles of several contributions in the performances measured under intense light illumination.The relationship between optimum mobility ratio (β) and lower trap-state density (Nt) in bled polymers: fullerene structures with device efficiency at various temperature ranges (300-400 K) has also been investigated. The properties result in lower series resistance, lower trap-assist recombination, longer carrier lifetime, longer excitons diffusion length, and thus higher device efficiency. Furthermore, the impact of charge carrier transport and collection behaviours on a typical interpretation of ohmic contact dependence in photovoltaic parameters is thoroughly investigated. The outcome revealed a stable η of 6.27% with a 250 nm thick absorber, which may be interpreted as a coupled framework for effective optimization strategies to accomplish balance between photogeneration and charge carrier recombination.