Mössbauer instruments were included on the Mars Exploration Rover (MER) Mission to determine the mineralogical composition, diversity, and oxidation state of Fe-bearing igneous materials and alteration products. A total of 16 Fe-bearing phases (mutually consistent with bulksample chemistry) were identified, including Fe associated with the rock-forming minerals olivine, pyroxene, magnetite, ilmenite, and chromite and alteration products including Fe 3+bearing oxyhydroxides (nanophase ferric oxide, hematite, and goethite) and sulfates (jarosite and an unassigned Fe 3+ sulfate phase), and Fe 2+ carbonate. Igneous rock types ranged from olivinepyroxene and olivine-pyroxene-magnetite basalts to ultramafic rocks at Gusev Crater. Jarositehematite bedrock was pervasive at Meridiani Planum, and concretions winnowed from the outcrop were mineralogically hematite. Because their structures contain hydroxyl, goethite and jarosite provide mineralogical evidence for aqueous processes on Mars, and jarosite and Fe 3+sulfate are evidence for acid-sulfate processes at both Gusev Crater and Meridiani Planum. A population of rocks on the Meridiani Planum outcrop was identified as iron and stony meteorites by the presence of Fe metal (kamacite) and the sulfide troilite. The MER mission demonstrates that Mössbauer spectrometers landed on any Fe-bearing planetary surface provide first-order information on igneous provinces, alteration state, and alteration style and provide wellconstrained criteria for sample selection on planetary sample-return missions including planets, moons, and asteroids.