Amberlite IR 120H<sup>+</sup> Catalyzed N‐C/C‐N Coupled Cylization Strategy to Give Imidazoles: Design and Fabrication of Organic Nanomaterial with AFM Imaging

Chakraborty, Mithun; Deb, Barnali; Dey, Bapi; Hussain, Syed Arshad; Maiti, Dilip K.; Majumdar, Swapan

doi:10.1002/slct.201601596

Cited by 9 publications

(1 citation statement)

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“…Imidazole and its derivatives involve one pot and the multicomponent reaction of substituted benzaldehyde, benzil, and ammonium acetate by using a PEG-SOCl as a green catalyst in aqueous media at room temperature or under microwave irradiation. The various synthetic methods have been developed for the synthesis of imidazole derivatives in the presence of different catalysts such as poly (4-vinylpyridine) supported TiCl 4 or [P 4 -VP]-Ti(IV) 25 , Amberlite IR 120H+ 26 , Appel reagent (Ph 3 P/CCl 4 ) 27 , Sulfonic Acid Magnetic Graphene Oxide (Fe3O4@GO-Pr-SO 3 H) 28 , Fly Ash Supported Bi 2 O 3 -ZnO 29 , Pyrrolidinium Hydrogen Sulfate (PHS) as the ionic liquid catalyst 30 , Pd/AlO(OH) NPs 31 , Urea/Hydrogen Peroxide (UHP) 32 , Nano-Zirconia (nano ZrO 2 ) 33 , Silver nanoparticles 34 , Copper Oxide nanoparticles 35 etc.…”

Section: Introductionmentioning

confidence: 99%

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2023

IJPSR

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A facile, highly efficient, simple, and convenient method for synthesizing 2, 4, 5-trisubstituted imidazole derivatives from the condensation of various substituted benzaldehyde, benzil, and ammonium acetate by using a catalytic amount of PEG-SOCl in the presence of water at room temperature or under microwave irradiation. PEG-SOCl is an effective heterogeneous catalyst and easy to separate. We have investigated that PEG-SOCl catalytic system was excellent recycled and reused three times without any loss of catalytic activity. PEG-SOCl act as a green catalyst, low-cost, non-volatile, non-hazardous, environmental friendly catalyst, and water is a green solvent reaction carried out at room temperature or under microwave radiation method shows greater advantages because it has contributed in the green chemistry aspects. The prepared catalyst was analyzed by analytical methods such as infrared spectrum (IR), X-Ray diffraction pattern (XRD), thermo-gravimetric analysis (TGA), and BET surface analysis. Spectroscopic techniques identified the synthesized pure product (1j), including infra-red (IR) spectrum, 1 H and 13 C NMR spectrum and Mass (LC-MS) spectrometry.

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Section: Introductionmentioning

confidence: 99%

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2023

IJPSR

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Catalytic Synthesis of 1,2,4,5‐Tetrasubstituted 1H‐Imidazole Derivatives: State of the Art

et al. 2019

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1,2,4,5-Tetrasubstituted-1H-imidazoles are a large family of heteroarene derivatives that are known to include natural products isolated from marine sponges and synthetic compounds possessing a broad range of biological and pharmacological properties. Consequently, a great deal of attention has been given to the synthesis of these heteroarenes and reviews covering some synthetic aspects of this topic have been published in recent years. However, none of these reviews provides a comprehensive overview of the several catalytic methods developed in the literature for the preparation of this important class of heteroarenes. This article review with 469 references, 63% of them being related to the period 2010-2017, aims to provide an updated critical picture of the catalytic processes reported in the literature up to the end of 2017 for the synthesis of 1,2,4,5-tetrasubstituted-1H-imidazoles illustrating these protocols and their characteristic features such as scope, efficiency, versatility, and limitations. The review also summarizes the mechanisms of the catalytic processes proposed for many of the reported processes.

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BMIm[OH] Catalyzed Rapid, Mild and Improved Protocol for the Synthesis of 3‐Hydroxy‐3‐(nitroalkyl)indolin‐2‐one Derivatives in Water

et al. 2019

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A sustainable route for the Henry reaction of isatins with nitromethane or nitroethane to afford 3‐hydroxy‐3‐(nitroalkyl)indolin‐2‐ones was developed by the catalysis of 1‐butyl‐3‐methyl imidazolium hydroxide (BMIm[OH]) ionic liquid in water‐SDS system. Incorporation of SDS in the reaction medium enhances the reaction rate by suppressing the solubility issues for different substrates particularly for N‐alkylated isatins. This method provides high yield of the condensation product in a shorter reaction time under a very mild condition and in a multi‐gram scale reaction. Moreover, recyclability of the catalyst ionic liquid as well as reaction medium including surfactant makes the present protocol environmentally benign.

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Amberlite IR 120H⁺ Catalyzed N‐C/C‐N Coupled Cylization Strategy to Give Imidazoles: Design and Fabrication of Organic Nanomaterial with AFM Imaging

Cited by 9 publications

References 55 publications

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Catalytic Synthesis of 1,2,4,5‐Tetrasubstituted 1H‐Imidazole Derivatives: State of the Art

BMIm[OH] Catalyzed Rapid, Mild and Improved Protocol for the Synthesis of 3‐Hydroxy‐3‐(nitroalkyl)indolin‐2‐one Derivatives in Water

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Amberlite IR 120H+ Catalyzed N‐C/C‐N Coupled Cylization Strategy to Give Imidazoles: Design and Fabrication of Organic Nanomaterial with AFM Imaging

Cited by 9 publications

References 55 publications

Untitled

Untitled

Catalytic Synthesis of 1,2,4,5‐Tetrasubstituted 1H‐Imidazole Derivatives: State of the Art

BMIm[OH] Catalyzed Rapid, Mild and Improved Protocol for the Synthesis of 3‐Hydroxy‐3‐(nitroalkyl)indolin‐2‐one Derivatives in Water

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Amberlite IR 120H⁺ Catalyzed N‐C/C‐N Coupled Cylization Strategy to Give Imidazoles: Design and Fabrication of Organic Nanomaterial with AFM Imaging