Amine Acyl Manganese Tetracarbonyl Complexes

Olefin and Acetylene Complexes of Transition Metals.

“…A similar effect has been noted with other ligands in the manganese carbonyl series (153). If a coordinated double bond was present initially in the -bonded complex, this may be set free in the above process.…”

Oxidative addition of methyl iodide to monosubstituted and disubstituted derivatives of ruthenium pentacarbonyl: preparation of neutral and ionic complexes of ruthenium

“…The solvents («-hexane, «-heptane, benzene, CH2C12, diethyl ether, acetone) were dehydrated by conventional methods19 and deaerated by bubbling with nitrogen. Tetrahydrofuran (THF) was purified as described in ref 20 and freshly distilled before use. CH3I was purified as described in ref 21 and stabilized with Hg.…”

Kinetic and thermodynamic studies of carbon monoxide insertion in alkylosmium(II) complexes and comparison with iron(II) and ruthenium(II) isoelectronic complexes

“…11 Tetrahydrofuran (thf) was purified as described in ref. 12 and freshly distilled before use. Ethylene glycol dimethyl ether was purified with sodium thiosulfate and dried with LiAlH 4 .…”