Aminobutadienes. (II) Synthesis of 2-Phthalimido-1, 3-but-adiene and 2-Succinimido-1, 3-butadiene

Terada, Akira; Takahashi, Shozi

doi:10.1246/nikkashi1948.83.4_485

Nippon Kagaku Zasshi

1962

DOI: 10.1246/nikkashi1948.83.4_485

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Aminobutadienes. (II) Synthesis of 2-Phthalimido-1, 3-but-adiene and 2-Succinimido-1, 3-butadiene

Akira Terada¹,

Shozi Takahashi²

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1967

1990

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Aminobutadienes. V. Polymers of 1‐phthalimido‐1,3‐butadiene and 1‐succinimido‐1,3‐butadiene

Terada¹,

Murata²

1967

J. Polym. Sci. A‐1 Polym. Chem.

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The radical polymerizations of 1‐phthalimido‐1,3‐butadiene (1‐PB) and 1‐succinimido‐1,3‐butadiene (1‐SB) were carried out in bulk and in solution. The polymers obtained had reduced viscosities in the ranges of 1.0–4.0 (1‐PB) and 0.2–0.6 (1‐SB). Both polymers had a similar softening point of 190–200°C. The radical polymerization of 1‐phthalimido‐1,3‐butadiene clearly showed a tendency to give crosslinked polymer. Steric arguments about these polymer structures as a result of the infrared and ozonolysis data led to the conclusion that these polymers contained approximately 20% of the 3,4 form but no 1,2 configuration, and, therefore, that the 1,4 addition was preferred.

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Aminobutadienes. V. Polymers of 1‐phthalimido‐1,3‐butadiene and 1‐succinimido‐1,3‐butadiene

Terada¹,

Murata²

1967

J. Polym. Sci. A‐1 Polym. Chem.

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N-DIENYL AMIDES AND LACTAMS: PREPARATION AND DIELS-ALDER REACTIVITY

Smith

1990

Organic Preparations and Procedures International

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Aminobutadienes. (II) Synthesis of 2-Phthalimido-1, 3-but-adiene and 2-Succinimido-1, 3-butadiene

Cited by 2 publications

References 0 publications

Aminobutadienes. V. Polymers of 1‐phthalimido‐1,3‐butadiene and 1‐succinimido‐1,3‐butadiene

Aminobutadienes. V. Polymers of 1‐phthalimido‐1,3‐butadiene and 1‐succinimido‐1,3‐butadiene

N-DIENYL AMIDES AND LACTAMS: PREPARATION AND DIELS-ALDER REACTIVITY

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