Aminodiacetic water-soluble polymer–metal ion interactions

Rivas, Bernabé L.; Maureira, Antonio; Mondaca, M. A.

doi:10.1016/j.eurpolymj.2008.05.001

Cited by 24 publications

(14 citation statements)

References 24 publications

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“…Interactions between polymers and different metal ions are an interesting field of study because of their potential analytical and technological applicability. Water‐insoluble resins have been extensively used to selectively concentrate and separate metal ions from water solutions 1, 2…”

Section: Introductionmentioning

confidence: 99%

Swelling behavior and metal ion retention from aqueous solution of hydrogels based on N‐1‐vinyl‐2‐pyrrolidone and N‐hydroxymethylacrylamide

Marambio

Pizarro

Jeria‐Orell

et al. 2009

J of Applied Polymer Sci

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Hydrophilic copolymer gels were prepared by free-radical copolymerization of 1-vinyl-2-pyrrolidone (NVP) and N-hydroxymethyl acrylamide (HMAm). The ratios of both monomers and crosslinker agent (CA) were varied, and the effect of external stimuli such as pH of the swelling media and inorganic ion interaction were investigated. The gels showed a pH-responsive behavior. The interactions of inorganic ions with the hydrophilic hydrogels were determined as a function of pH, copolymer composition, and variation of the composition crosslinking degree. Additionally, a decrease of the pH of the solution caused a decrease in the equilibrium degree of swelling of the copolymer gels. The capacity to remove several metal ions such as Cu(II), Cr(III), Co(II), Zn(II), Ni(II), Cd(II), and Fe(III) in the aqueous phase was determined by using the liquid-phase polymer-based retention (LPR) technique. In addition, the copolymers and their complexes with transition metal ions were characterized by the monomer reactivity ratios by using the Kelen-Tü dö s method, elemental analysis, FTIR and 1 H-NMR spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. Based on the results of swelling and retention capacity of metal ions of poly(NVP-co-HMAm), it was concluded that the swelling and retention capacity properties of the hydrogels depends on the reaction environment's pH. This is regarded as a functional hydrogel, which could be employed as biodegradable materials for applications in agriculture chemicals and as drug delivery systems.

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Section: Introductionmentioning

confidence: 99%

Swelling behavior and metal ion retention from aqueous solution of hydrogels based on N‐1‐vinyl‐2‐pyrrolidone and N‐hydroxymethylacrylamide

Marambio

Pizarro

Jeria‐Orell

et al. 2009

J of Applied Polymer Sci

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“…acid has been chosen as a monomer, which is also hydrophilic in nature [38][39][40]. 2-Acrylamidoglycolic acid (AGA) refers to a class of acrylamides containing OH, COOH and CONH functional groups that shows excellent selectivity in separating apatite from siliceous gangue [41].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and properties of a water soluble graft (chitosan-g-2-acrylamidoglycolic acid) copolymer

Yadav

Sand

Behari

2012

International Journal of Biological Macromolecules

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“…IDA can be easily grafted to polymer chain, and the applications of IDA functionalized polymer had been reported in recent years. 5,6 Because of the good metal-ion adsorption performance, 7 polymer-IDAmetal complexes show widespread availability in various fields, such as separation of rare earth elements, 8 catalyst system, 9 protein separation, 10,11 and so on. To introduce IDA into polymer chain, the traditional method is to graft epoxides like epichlorohydrin 12 and glycidyl methacrylate 3,13 to polymer main chain firstly, and then graft IDA molecules by opening the epoxy ring.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, characterization, and application of polyethersulfone bound‐iminodiacetic acid

Cao

Cheng

Yin

et al. 2010

J of Applied Polymer Sci

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A new method to introduce iminodiacetic acid (IDA) onto polyethersulfone (PES) matrix through chlorosulfonation was described in this work, and the prepared PES-IDA was used as adsorbent for the removal of metal ions from aqueous solutions. Chlorosulfonic groups (ASO 2 Cl) were introduced onto PES first, then IDA was grafted onto PES by using the interactions between the chlorosulfonic group and the imino group of IDA. The grafted IDA was characterized by fourier transform infrared measurement, X-ray photoelectron spectroscopy analysis, and thermogravimetric analysis spectra. The adsorbed amounts by the PES-IDA for Cu 2þ and Ag þ were 3.44 mg/g and 7.09 mg/g, respectively. The PES-IDA adsorbent may expand the usage of PES in purification fields and could make some potential contributions to the polymer-based adsorbents.

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Aminodiacetic water-soluble polymer–metal ion interactions

Cited by 24 publications

References 24 publications

Swelling behavior and metal ion retention from aqueous solution of hydrogels based on N‐1‐vinyl‐2‐pyrrolidone and N‐hydroxymethylacrylamide

Swelling behavior and metal ion retention from aqueous solution of hydrogels based on N‐1‐vinyl‐2‐pyrrolidone and N‐hydroxymethylacrylamide

Synthesis and properties of a water soluble graft (chitosan-g-2-acrylamidoglycolic acid) copolymer

Synthesis, characterization, and application of polyethersulfone bound‐iminodiacetic acid

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