Aminoethyl-Functionalized Cyclopentadienyl Complexes of d-Block Elements

Jutzi, Peter; Redeker, Thomas

doi:10.1002/(sici)1099-0682(199806)1998:6<663::aid-ejic663>3.0.co;2-y

Eur. J. Inorg. Chem.

1998

DOI: 10.1002/(sici)1099-0682(199806)1998:6<663::aid-ejic663>3.0.co;2-y

|View full text |Cite

Aminoethyl-Functionalized Cyclopentadienyl Complexes of d-Block Elements

Peter Jutzi¹,

Thomas Redeker

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2000

2002

Publication Types

Select...

Article5

Relationship

Self Cite1

Independent4

Authors

Journals

Cited by 127 publications

References 129 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Dialkylaminoethyl-funktionalisierteansa-Zirconocendichloride: Präkatalysatoren zur Steuerung der Molekulargewichtsverteilung von Polyethylen

et al. 2000

Self Cite

View full text Add to dashboard Cite

28.098; 4118 unabhängige Reflexe; Volle-Matrix-kleinste-Fehlerquadrate-Verfeinerung; R-Werte [I b 2s(I)]: R 1 0.0443, wR 2 0.1001; max. Restelektronendichte: 0.419 e À3 . 10 a: C 20 H 23 FeNO 6 , M r 429.24 g mol À1 , triklin, Raumgruppe P1 Å , l 0.71073 , a 8.232(4), b 10.759(5), c 12.318(5) , a 74.98(3), b 84.86(4), g 73.25(4)8, V 1008.9(8) 3 , Z 2, 1 ber. 1.413 g cm À3 , m 0.783 mm À1 , T 293(2) K, q-Bereich: 1.71 ± 25.998; 3966 unabhängige Reflexe; Volle-Matrix-kleinste-Fehlerquadrate-Verfeinerung; R-Werte [I b 2s(I)]: R 1 0.0408, wR 2 0.1036; max. Restelektronendichte: 0.431 e À3 . 10 b: C 20 H 23 FeNO 6 , M r 429.24 g mol À1 , monoklin, Raumgruppe C2/c, l 0.71073 , a 19.630(10), b 15.928(11), c 15.375(5) , b 124.12(2)8, V 3979.8(37) 3 , Z 8, 1 ber.

show abstract

Dialkylaminoethyl-funktionalisierteansa-Zirconocendichloride: Präkatalysatoren zur Steuerung der Molekulargewichtsverteilung von Polyethylen

et al. 2000

Self Cite

View full text Add to dashboard Cite

show abstract

The Hemilabile [2-(Dimethylamino)ethyl]cyclopentadienyl Ligand and Nickel: Preparation and Structural Analysis of New Cationic and Neutral Complexes

Segnitz

Winter

Merz

et al. 2000

Eur. J. Inorg. Chem.

View full text Add to dashboard Cite

Chelate Complexes of Functionalized Cycloheptatrienyl Ligands: 17- and 18-Electron Molybdenum Complexes with Linked Cycloheptatrienyl−Phosphane Ligands and Their Use in Transition Metal Catalysis

Tamm

Baum

Lügger

et al. 2002

Eur. J. Inorg. Chem.

View full text Add to dashboard Cite

The synthesis of P-functionalized molybdenum chelate complexes incorporating the linked cycloheptatrienyl− phosphane ligand [2-(diphenylphosphanyl)phenyl]cycloheptatrienyl, o-Ph 2 P−C 6 H 4 −C 7 H 6 , is described. The air-stable ligand precursor [2-(cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane (2) can be obtained in large quantities by addition of lithiated 2-BrC 6 H 4 PPh 2 (1) to the tropylium cation C 7 H 7 + . Hydride abstraction employing the trityl cation, Ph 3 C + , results in the formation of the tricyclic phosphonium salt 3. The P-functionalized cycloheptatriene 2 acts as an eight-electron ligand on reaction with Mo(CO) 6 to afford the cycloheptatriene−phosphane complex [(o-Ph 2 PC 6 H 4 -η 6 -C 7 H 7 )Mo(CO) 2 (P−Mo)] (4) as a single, chiral regioisomer, which undergoes clean hydride abstraction on treatment

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Aminoethyl-Functionalized Cyclopentadienyl Complexes of d-Block Elements

Cited by 127 publications

References 129 publications

Dialkylaminoethyl-funktionalisierteansa-Zirconocendichloride: Präkatalysatoren zur Steuerung der Molekulargewichtsverteilung von Polyethylen

Dialkylaminoethyl-funktionalisierteansa-Zirconocendichloride: Präkatalysatoren zur Steuerung der Molekulargewichtsverteilung von Polyethylen

The Hemilabile [2-(Dimethylamino)ethyl]cyclopentadienyl Ligand and Nickel: Preparation and Structural Analysis of New Cationic and Neutral Complexes

Chelate Complexes of Functionalized Cycloheptatrienyl Ligands: 17- and 18-Electron Molybdenum Complexes with Linked Cycloheptatrienyl−Phosphane Ligands and Their Use in Transition Metal Catalysis

Contact Info

Product

Resources

About