Aminopyridine coordinated iron phthalocyanines: Synthesis, structure, and characterization

Fang, Xin; Yang, Feng-Ju; Yu, Haiyang; Chen, Naisheng; Huang, Mingdong; Wang, Jundong

doi:10.1016/j.inoche.2009.05.018

Cited by 5 publications

(1 citation statement)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For PcZn II , PcCo II , and PcFe II the vast majority of axial ligands (L) that have been reported are N-donors such as imidazole (Im), N -methyl imidazole (MeIm), pyridine (py), 4,4′-bipyridine (bpy), pyrazine (pyz), or piperidine (pip). 26–37 Based on a search of the Cambridge Structural Database (CSD), there are a few examples of carbon-donor axial ligands on PcFe II , but none exist for PcZn II or PcCo II . 38,39 All of these axial ligands were shown to improve the solubility of the unsubstituted PcM without inducing significant deformations to the Pc ring.…”

Section: Introductionmentioning

confidence: 99%

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Kidd,

Zhou,

Warren

et al. 2024

Dalton Trans.

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Kidd,

Zhou,

Warren

et al. 2024

Dalton Trans.

View full text Add to dashboard Cite

show abstract

Coordination Polymer of Manganese(II) Phthalocyanine with 4,4′‐Bipyridyl: Synthesis, Crystal Structure, and Physical Properties

et al. 2016

View full text Add to dashboard Cite

A coordination polymer of metal(II) phthalocyanine (Pc) with a pyridine-containing bidentate ligand has been obtained for the first time as single crystals. It has the composition (Mn II Pc·4,4′bpy) n ·(4C 6 H 4 Cl 2 ) n (1) and contains manganese(II) phthalocyanine and 4,4′-bipyridyl (4,4′-bpy). Optical and mag- [a] 5445 netic properties of the polymer have been studied. The coordination of bpy to Mn II Pc produces new absorption bands in the NIR range, which can be attributed to Mn I Pc + and Mn III Pcspecies. The Mn II atoms have an intermediate S = 3/2 spin state in 1 and show weak ferromagnetic coupling of spins.

show abstract

Syntheses, structural characterization, and thermal behaviour of metal complexes with 3-aminopyridine as co-ligands

et al. 2020

View full text Add to dashboard Cite

Six mixed metal complexes with 3-aminopyridine (3-ampy) as a co-ligand have been synthesized: catena-{[M(μ2-3-ampy)(H2O)4]SO4·H2O} (M=Ni (1) and Co (2)), [Co(3-ampy)4(NCS)2] (3), [Co(3-ampy)2(NCS)2] (4), [Co(3-ampy)4(N3)2] (5) and mer-[Co(3-ampy)3(N3)3] (6), (NCS−=isothiocyanate ion, N3− azide ion), and characterized by physio-chemical and spectroscopic methods as well as single crystal X-ray and powder diffraction. In the isostructural complexes 1 and 2 single μ2-3-ampy links the Ni(II) and Co(II) centers into polymeric chains. The mononuclear Co(II) and Co(III) pseudohalide complexes 3–6 reveal only terminal 3-ampy ligands. The 3-ampy ligands form supramolecular hydrogen bonded systems via their NH2-groups and non-covalent π-π ring-ring interactions via their pyridine moieties. Thermoanalytical properties were investigated for 1–3. Graphic abstract

show abstract

Aminopyridine coordinated iron phthalocyanines: Synthesis, structure, and characterization

Cited by 5 publications

References 5 publications

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Coordination Polymer of Manganese(II) Phthalocyanine with 4,4′‐Bipyridyl: Synthesis, Crystal Structure, and Physical Properties

Syntheses, structural characterization, and thermal behaviour of metal complexes with 3-aminopyridine as co-ligands

Contact Info

Product

Resources

About