Ammonium Saccharin

The saccharinate anion: a versatile and fascinating ligand in coordination chemistry

“…This is the case of Na(sac).2/3H 2 O and Mg(sac) 2 .7H 2 O 5 of K 2 Na(sac) 3 .H 2 O 6 and also of NH 4 (sac) 7 .…”

Synthesis, characterization and crystal structure of a novel 3D network triorganotin(IV) polymer containing two types of macrocycles

“…As we know organotin complexes are attracting more and more attention due to their wide industrial applications and antitumor activities [7]. The chemistry of novel organotin(IV) polymers based on covalent interactions [8][9][10][11][12] or supramolecular contacts (such as hydrogen bonding and/or pp stacking interactions) [13][14][15][16] has been actively investigated too, but most of the reported polymeric systems are, 1D chain or 2D network structures, and some of them are constructed through supramolecular contacts. So far, few multidimensional organotin coordination polymers based on covalent interactions have been studied.…”

Synthesis, crystal structure and magnetic property of a new layered copper(II) complex with picolinic acid N-oxide built from Cu2O2 dimer units

“…Such type of coordination mode has not been reported yet. In most metal complexes, the picolinato N-oxide ligand is bidentate and only forms a six-membered chelating ring using the N-oxide group and one carboxylate oxygen atom [8][9][10]15]. The L ligand in its Sn(II) complex is bidentate bridging, thus no chelating ring is formed [11].…”

“…In an effort to explore new copper(II) complexes with novel magnetic properties, we selected the picolinic acid N-oxide (HL) as a bridging ligand. Although a number of transition metal complexes with picolinic acid N-oxide have been reported [8][9][10][11][12][13][14], to the best of our knowledge, only one mononuclear copper(II) complex, [Cu(L) 2 (H 2 O) 2 ], has been reported [15]. Reaction of CuCl 2 with HL in acetone/THF mixed solvent afforded a new copper complex, [Cu(L)Cl(H 2 O)] 2 , whose structure features a layer built from Cu 2 O 2 dimeric units.…”