their label-free and nondestructive analysis capabilities benefit from unique characteristic spectra of molecules under test. [1][2][3][4] Tremendous efforts have been made in free-space MIR spectroscopy for applications ranging from personal healthcare to environmental monitoring. [5][6][7][8][9][10] Toward future miniaturized chip-scale sensing systems, nanophotonic waveguide platforms provide an attractive approach for costeffective dense integration. [11,12] In the past decades, silicon photonics becomes a viable solution to miniaturize optical systems due to its compatibility with the mature complementary-metal-oxide-semiconductor fabrication infrastructure. [13][14][15][16] Despite the conventional silicon-on-insulator (SOI) platform has been widely adopted in the near-infrared (NIR) telecommunication band, the presence of the buried oxide (BOX) limits its effectiveness in MIR photonics due to the severe absorption issue. In addition to transparency considerations, the optical properties of intrinsic silicon (Si) might be incapable of simultaneously providing all the functionalities desired for photonic integrated circuits (PICs) such as on-chip light modulation and nonlinear optics application [17] due to the centrosymmetric crystal structure. Especially, optical phase shifters are important for phased array beam-steering in free-space communication, light detection and ranging (LIDAR) applications, [18,19] on-chip Fourier transform infrared (FTIR) spectrometers, [20,21] and photonic neural network. [22] State-ofthe-art Si modulators mainly realize phase modulation through the plasma dispersion effect of free carriers in doped Si. [23][24][25] While relatively efficient, these devices suffer from considerable insertion loss and spurious amplitude modulation. The concurrent modulation of real and imaginary part of the refractive index becomes a major restriction when proliferating them in a coherent photonic network in which adjustments of purely optical phase are required. Phase shifting has been also achieved through the thermo-optic effect in Si, but they are inherently slow and constrained by stringent tradeoffs between modulation speed and power dissipation. [26,27] Alternately, by building mature Si photonic devices on MIR-transparent materials with strong Pockels effect (otherwise known as the linear electrooptic effect), phase modulation can be also performed in a lowloss, high compact, and high energy-efficient manner.
Mid-infrared spectroscopy is an emerging technique in various applicationssuch as molecule identification and label-free chemical sensing. Integrated photonic platforms have a promising potential to perform miniaturized spectroscopic sensing with the advantage of compact footprint, low cost, and low power consumption. As an essential building block for integrated photonics, on-chip phase shifter plays an important role in mid-infrared spectroscopic systems, enabling signal processing and spectrum analysis. However, the implementation of effective pure phase modulation in mid-infrared...