Amphiphilic A3B3 miktoarm star polymer: synthesis and micellization study by fluorometry, TEM and DLS techniques

Rezaei, Abbas; Aminian, Faezeh; Behniafar, Hossein

doi:10.1007/s13233-023-00177-y

Macromol. Res.

2023

DOI: 10.1007/s13233-023-00177-y

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Amphiphilic A3B3 miktoarm star polymer: synthesis and micellization study by fluorometry, TEM and DLS techniques

Abbas Rezaei,

Faezeh Aminian,

Hossein Behniafar

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2024

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Cited by 4 publications

References 32 publications

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Novel amphiphilic (AB)₃‐type star block polymer: Synthesis and micellization study

Hamzeheipour,

Rezaei,

Behniafar

2024

J of Applied Polymer Sci

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An amphiphilic three‐armed star polymer was synthesized through the polar cycloaddition reaction of a polyethylene glycol‐based macro‐triazide with an Yne‐terminated polycaprolactone in a molar ratio of 1:3 (click chemistry). Thus, each arm is itself a di‐block copolymer branched from the core, which is a 1,3,5‐triazine ring. The attachment of the pre‐synthesized hydrophobic segments to the hydrophilic segments in each arm leads to the creation of a 1,2,3‐triazole ring in the structure. Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (H‐NMR) spectroscopies were used to verify the structures. The micellization process of the prepared amphiphilic polymer was investigated in aqueous medium. For this purpose, the critical micelle concentration (CMC) was specified by the fluorometric method. Using the transmission electron microscopy (TEM) technique, it was observed that spherical self‐assemblies with a mean diameter of <100 nm are formed from the aggregation of the amphiphilic macromolecules. In addition, the hydrodynamic diameter (H) of the polymeric micelles and their size distribution were examined by dynamic light scattering (DLS) technique.

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Novel amphiphilic (AB)₃‐type star block polymer: Synthesis and micellization study

Hamzeheipour,

Rezaei,

Behniafar

2024

J of Applied Polymer Sci

Self Cite

View full text Add to dashboard Cite

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Synthesis and study of AB2-type miktoarm star-shaped nanomaterials having glycine as an arm

Panchal,

Vasava

2024

J Polym Res

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A novel water-soluble quinoxalino[2,3-a] phenazine-based organic NIR photothermal agent for cancer phototherapy application

Liu,

Zhao,

Ding

et al. 2024

J Chem Sci

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Amphiphilic A3B3 miktoarm star polymer: synthesis and micellization study by fluorometry, TEM and DLS techniques

Cited by 4 publications

References 32 publications

Novel amphiphilic (AB)₃‐type star block polymer: Synthesis and micellization study

Novel amphiphilic (AB)₃‐type star block polymer: Synthesis and micellization study

Synthesis and study of AB2-type miktoarm star-shaped nanomaterials having glycine as an arm

A novel water-soluble quinoxalino[2,3-a] phenazine-based organic NIR photothermal agent for cancer phototherapy application

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Product

Resources

About

Amphiphilic A3B3 miktoarm star polymer: synthesis and micellization study by fluorometry, TEM and DLS techniques

Cited by 4 publications

References 32 publications

Novel amphiphilic (AB)3‐type star block polymer: Synthesis and micellization study

Novel amphiphilic (AB)3‐type star block polymer: Synthesis and micellization study

Synthesis and study of AB2-type miktoarm star-shaped nanomaterials having glycine as an arm

A novel water-soluble quinoxalino[2,3-a] phenazine-based organic NIR photothermal agent for cancer phototherapy application

Contact Info

Product

Resources

About

Novel amphiphilic (AB)₃‐type star block polymer: Synthesis and micellization study

Novel amphiphilic (AB)₃‐type star block polymer: Synthesis and micellization study