Polyvinylidene fluoride (PVDF) is considered to be one of the most promising candidates for next-generation wearable sensors; however, the sensing ability of PVDF is worth expanding beyond its ferroelectricity. In this work, PVDF is used as matrix material for humidity detection by adding two other ingredients: lithium chloride (LiCl) and polyvinyl alcohol (PVA), optimal concentrations of LiCl and PVA are found by systematic investigation of the impact of the two inclusions on humidity sensing ability of the composites.