With the development of cloud computing and the advent of the Web 2.0 era, composing a set of Web services as a service process is becoming a common practice to provide more functional services. However, a service process involves multiple service invocations over the network, which incurs a huge time cost and could become a bottleneck to performance. To accelerate its execution, we propose an engine-side cache-blockbased service process caching strategy (CBPCS). It is based on, and derives its advantages from, three key ideas. First, the invocation of Web services embodies semantics, which enables the application of semanticbased caching. Second, cache blocks are identified from a service process, and each block is equipped with a separate cache so that the time overhead of service invocation and caching can be minimized. Third, a replacement strategy is introduced taking into account time and space factors to manage the space allocation for a process with multiple caches. The algorithms and methods used in CBPCS are introduced in detail. Moreover, how CBPCS can be applied to multiple service process models is also investigated. Finally, CBPCS is validated via comparison experiments, which shows the considerable improvements of CBPCS over other strategies.