An AIE-active acridine functionalized spiro[fluorene-9,9′-xanthene] luminophore with mechanoresponsive luminescence for anti-counterfeiting, information encryption and blue OLEDs

Liang, Xiaozhong; Dong, Bizheng; Wang, Hua; Zhang, Zheng; Wang, Sijing; Li, Jie; Zhao, Bo; Li, Zhijun; Xing, Yifan; Guo, Kunpeng

doi:10.1039/d2tc00876a

Cited by 16 publications

(4 citation statements)

References 35 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…By combing the spiro[fluorene-9,90-xanthene] and 9,9-dimethyl-9,10-dihydroacridine, Guo at al. prepared an AIE-active molecule (SFX-Ad) [43]. The SFX-Ad displays mechanoresponsive properties, and an obvious enhancement of the luminescence is companied with the crystal-to-amorphous transition.…”

Section: Aiegensmentioning

confidence: 99%

See 1 more Smart Citation

Emerging Luminescent Materials for Information Encryption and Anti-Counterfeiting: Stimulus-Response AIEgens and Room-Temperature Phosphorescent Materials

Li,

Gao

2023

Chemosensors

View full text Add to dashboard Cite

Information encryption and anti-counterfeiting play an important role in many aspects of daily life, such as in minimizing economic losses, protecting secure communication and public security, and so on. Owing to the high information capacity and ease of operation, luminescent materials for advanced information encryption and anti-counterfeiting are essential to meet the increasing demand on encryption security. Herein, we summarize two emerging luminescent materials for information encryption and anti-counterfeiting—AIE materials and room-temperature phosphorescent materials. Finally, we discuss the opportunities and anticipations of these two information encryption and anti-counterfeiting materials.

show abstract

Section: Aiegensmentioning

confidence: 99%

“…Various nanomaterials, such as metal clusters and carbon dots (CDs), have already exhibited typical AIE property and could be regarded as functional AIEgens. Recently, many AIE CDs [42,43,45,46,48,52,54]…”

Section: Aie Carbon Dotsmentioning

confidence: 99%

Emerging Luminescent Materials for Information Encryption and Anti-Counterfeiting: Stimulus-Response AIEgens and Room-Temperature Phosphorescent Materials

Li,

Gao

2023

Chemosensors

View full text Add to dashboard Cite

show abstract

“…These unique characteristics make organic luminescent crystals a promising candidate in organic lightemitting diodes (OLEDs), organic field-effect transistors (OFETs), organic photovoltaic cells (OPVCs), sensors, data storage, and biological imaging. [15][16][17][18][19][20][21][22][23][24][25][26][27][28] In general, conventional conjugated small molecules suffer from an aggregation caused quenching (ACQ) effect in the condensed state, leading to a quenching phenomenon in luminescence. 29 This bottleneck has been broken with the discovery of aggregation-induced emission (AIE) by Tang and co-workers in 2001.…”

Section: Introductionmentioning

confidence: 99%

“…These unique characteristics make organic luminescent crystals a promising candidate in organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), organic photovoltaic cells (OPVCs), sensors, data storage, and biological imaging. 15–28…”

Section: Introductionmentioning

confidence: 99%

Organic luminescent crystals: role of packing structures and optical properties

Yin¹,

Pan²,

Zhang³

et al. 2023

Mater. Chem. Front.

View full text Add to dashboard Cite

show abstract

Investigation of Mechanochromic Luminescence of Pyrene‐based Aggregation‐Induced Emission Luminogens: Correlation between Molecular Packing and Luminescence Behavior

Varghese,

Yao,

Chen

2023

Chemistry An Asian Journal

View full text Add to dashboard Cite

To better understand the correlation between molecular structure and optical properties such as aggregation‐induced emission (AIE) and mechanochromic luminescence (MCL) emission, two new pyrene‐based derivatives with substitutions at the 4‐ and 5‐positions (1HH) and at the 4‐, 5‐, 9‐, and 10‐positions (2HH) were designed and synthesized. Cyano groups were introduced at the periphery of the synthesized compounds (1HCN, 1OCN, 1BCN, 2HCN, 2OCN, and 2BCN) to investigate the influence of these groups on the emission properties of the pyrene derivatives both in solution and in the solid state. The fluorescence emission performance of these compounds in water/acetone mixtures was simultaneously studied, revealing outstanding aggregation‐induced emission properties. The typical shift in emission maxima to higher values was attributed to J‐aggregate formation in the aggregate state. Careful investigation of the crystal structures demonstrated abundant and intense intermolecular interactions, such as C−H…π and C−H…N hydrogen bonds, contributing to the remarkable mechanochromic luminescence performance of these compounds. The MCL properties of all the compounds were investigated using powder X‐ray diffraction, and the remarkable mechanochromic properties were attributed to J‐aggregate phenomena in the solid state. These results provide valuable insights into the structure‐property relationship of organic MCL materials, guiding the design of efficient organic MCL materials.

show abstract

An AIE-active acridine functionalized spiro[fluorene-9,9′-xanthene] luminophore with mechanoresponsive luminescence for anti-counterfeiting, information encryption and blue OLEDs

Cited by 16 publications

References 35 publications

Emerging Luminescent Materials for Information Encryption and Anti-Counterfeiting: Stimulus-Response AIEgens and Room-Temperature Phosphorescent Materials

Emerging Luminescent Materials for Information Encryption and Anti-Counterfeiting: Stimulus-Response AIEgens and Room-Temperature Phosphorescent Materials

Organic luminescent crystals: role of packing structures and optical properties

Investigation of Mechanochromic Luminescence of Pyrene‐based Aggregation‐Induced Emission Luminogens: Correlation between Molecular Packing and Luminescence Behavior

Contact Info

Product

Resources

About