An alternative improved method for the homogeneous dispersion of CNTs in Cu matrix for the fabrication of Cu/CNTs composites

Abstract

Copper has a wide range of applications due to its excellent properties (high thermal and electrical conductivity). Carbon nanotubes (CNTs) are widely used as a reinforcing material due to their superior properties. Copper/Carbon nanotube (Cu/CNTs) composites show enhanced mechanical, electrical and thermal properties as compared to pure Cu and Cu composites. Hence, Cu/CNTs composites have tremendous applications. Cu/CNTs are being developed for use as antifungal and antimicrobial agents, which can lead to their further use in biomedical devices and implant materials. The versatility of this material is such that Cu/CNTs are being developed for use in ultra-large scale integrated circuits for use in the latest integrated circuits and semiconductor chips. The composite material is being used as heat sinks for various industries. Cu/CNTs are now also being employed as catalysts for various industrial reactions. Fuel cell electrodes based on Cu/CNTs are being developed to replace expensive Pt/Pdbased electrodes, currently being used. Another application in the energy sector is the use of Cu/CNTs in direct methanol fuel cells and in methanol gas reforming for H 2 production. These extensive applications provided motivation for the current work. However, these applications can only be realized if a stable and uniform Cu/CNTs composite powder can be made. The challenges in fabricating Cu/CNTs composites are: (1) homogeneous dispersion of CNTs in Cu matrix, (2) interfacial bonding between CNTs and Cu matrix and (3) retention of structural integrity of CNTs. Powder metallurgy (PM) has been widely used, but dispersion of Cu/CNTs remains an issue. We employed the molecular level mixing method (MLM), coupled with high energy ball milling (BM) to overcome above mentioned issues. To the best of our knowledge, this is a new process for the homogeneous dispersion of CNTs in copper and has been reported for the first time. To produce a homogenous mixture of Cu and CNTs, a combination of MLM and BM was used in the present work. This method involves using a Cu salt/CNTs mixture in desirable weight ratio (CNTs being were taken in a high concentration), followed by chemical reduction in aqueous medium using NABH 4 as reducing agent and EDTA as the oxidation control agent. The resultant mixture (Copper/ Carbon nanotube) was mixed with pure Cu using BM. The composites were fabricated using PM, in which the composite powders were first cold pressed at 500-550 MPa followed by sintering at 550-900°C in a vacuum of 10 -2 Torr. Characterization was carried out using SEM, XRD and HRTEM, and various mechanical properties were measured using a Universal testing Instron machine. Keywords Copper/Carbon nanotube composites Á Molecular level mixing Á High energy ball milling IntroductionCopper is a widely used metal and it has a wide range of applications owing to its excellent thermal and electrical properties. In the current age, the requirements of such

Carbon Nanotube (CNT)-Reinforced Metal Matrix Bulk Composites: Manufacturing and Evaluation

“…Considering that commercial CNTs are usually delivered in agglomerated form, different methods have to be employed to disaggregate and blend them with the metallic matrix material. There are a lot of dispersing and blending processes like magnetic stirring [40], nanoscale dispersion processing [18,21,41], colloidal mixing [6,16,22,[26][27][28][29][30][31][41][42][43][44][45][46][47][48][49], molecularlevel mixing [7,9,11,12,14,24,25,[50][51][52][53][54], particle composite system mixing [15,55], friction stir processing [56], layer stacking [57], ball milling [8,10,17,19,20,[22][23][24][32]…”

“…Using low energy ball milling, this unwanted effect can be reduced, but it will not vanish. The importance of a low defect density of CNTs will be discussed later on in entry 2.2 [8,10,17,19,20,[22][23][24][32][33][34][35][36]38,50,53,[58][59][60][61][62][63][64][65][66][67][68][69][70][71][72][73][74].…”

Electrical and mechanical properties of Cu-CNT nanocomposites sintered by microwave technique

“…The optimum sintering temperature and time for MMCs based on copper reinforced CNT were reported at 900 °C and 2 h, by previous researches [22,[42][43][44]. Therefore, in this work, conventional sintering process was carried out at a sintering temperature of 900 °C for 2 h, and the samples produced by microwave sintering method was selected for 20 min sintering time.…”

The effect of sintering temperature on Cu-CNTs nano composites properties produced by PM method

“…A broad range of studies have reported that CNTs improve the performance of ceramic and polymer matrix in the last decades [14][15], and researches on metal matrices reinforced with CNTs are to some extent restricted [16]. The main issue in the synthesis of metal-CNTs nanocomposites is to achieve a homogeneous dispersion of CNT powders in the metallic matrices [1][2][16][17]. However, many research groups have employed efficient methods to enhance dispersion.…”