The trend towards very shallow, submicron diffusion depths in the fabrication of silicon-diffused devices has revealed a number of new diffusion phenomena which form the subject of this review. The diffusion characteristics of some of the individual dopants involved (phosphorus, arsenic, boron and gallium) are first briefly surveyed, and then interactions between sequential diffusions are described in detail.The effects discussed include 'emitter-push' or 'push-out', which is the enhanced penetration of a base dopant, such as boron, directly beneath an emitter diffusion, and 'base retardation' which is where the diffused base-collector junction away from the emitter advances more rapidly than that directly beneath it. Also discussed are effects associated with buried marker layers, which also show evidence for enhanced diffusion directly beneath certain diffused emitters.On the basis of the evidence reviewed, it is suggested that anomalies connected with phosphorus diffusion, namely the rapidly diffusing phosphorus 'tail', the 'push-out' effect and the movement of buried marker layers are all linked and are consistent with the generation of a high supersaturation of point defects. The mechanism of generation, which has to account for enhancements in diffusivity of up to 100, and the identity of the defects are still in question, but it is argued that dislocation-related generation mechanisms can now be ruled out. Another general conclusion emerging from the review is that a 'depletion' or 'dip' is found in the base profile (boron or gallium) under either a phosphorus or arsenic emitter diffusion, and that most observations are consistent with that caused by the electric field generated by the diffusing emitter dopant. Finally, the causes of 'base retardation' are still not clear and the review suggests a number of areas for further study.