To accurately determine the temperature-dependent parameters of composites, a thermo-elastic parameter identification approach using thermal modal data is proposed in this article. The investigation is based on two hypotheses: (1) the structure is at steady-state temperature field, which means the temperature distribution is time independent; (2) temperature distribution can be determined in advance of thermo-elastic parameter identification, and thermal-related large deformation is not considered. The thermal-dependent elastic constants and thermal expansion coefficients are expressed as intermediate functions with the independent variable of temperature, perturbation method is adapted to calculate the sensitivity of thermal modal frequencies with respect to the intermediate variables, and variables with high sensitivity are selected as the identifying parameters. By constructing the intermediate function and calculating the relative sensitivity, thermo-elastic parameters are identified by minimizing the residual between experimental and analytical natural frequencies under thermal circumstance. Two different types of composite models are employed to verify the strategies of parameter identification. Results show that on the basis of the intermediate function, the proposed approach can be applied to identify the thermo-elastic parameters effectively.