Acid
fracturing is applied to increase the productivity of carbonate
formations. The acid creates rough fracture surfaces and channels
that keep the fractures open after closure. This study investigated
a chelating agent and HCl acid as acid fracturing fluids in three
different carbonates: Austin chalk, Indiana limestone, and Silurian
dolomite. The impact of rock hardness and surface roughness on conductivity
was thoroughly studied. We collected six core samples, two from each
type, with 1.5-in. × 6-in. dimensions. A saw was used to cut
the samples, creating smooth initial fracture surfaces. A Brinell
hardness tester (FH-9 model) was used to measure the rock strength,
while a Kruss high-resolution surface analyzer (SRA) was used to scan
the rock surfaces and measure the roughness. The acid fracturing treatment
was carried out using a coreflooding system at 100 °C and 1000
psi confining pressure. The fracture conductivity was measured before
and after treatment utilizing different flow rates (2.5–10
cc/min) and overburden pressures (1000–2500 psi). The reactivity
of acid with a rock was quantified by tracing the calcium ions in
the effluents collected from coreflooding outlet at a fixed time interval.
The analysis was conducted with inductively coupled plasma (ICP).
It is observed that rock hardness and roughness have a significant
impact on fracture conductivity. Also, the type of treating fluid
and rock determines the generated rock roughness, where higher reactivity
results in higher roughness and hence conductivity. Glutamic diacetic
acid (GLDA) chelating agent generated sufficient fracture conductivity
in chalk and limestone rocks, while HCl acid generated high conductivity
in the three rock types. This study sheds new insights on the selection
of the acid fracturing fluid for different carbonates, and less reactive
rocks such as dolomites are not good candidates to be treated with
chelating agents because of its low reactivity. Calcite rocks (i.e.,
limestone and chalk) can be treated with chelating agents or strong
acids.