2008
DOI: 10.1007/s10765-008-0485-y
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An Assessment of Thermodynamic Models for HFC Refrigerant Mixtures Through the Critical-Point Calculation

Abstract: An assessment of thermodynamic models for HFC refrigerant mixtures based on Helmholtz energy equations of state was made through critical-point calculations for ternary and quaternary mixtures. The calculations were performed using critical-point criteria expressed in terms of the Helmholtz free energy. For three ternary mixtures: difluoromethane (R-32) + pentafluoroethane (R-125) + 1,1,1,2-tetrafluoroethane (R-134a), R-125 + R-134a + 1,1,1-trifluoroethane (R-143a), and carbon dioxide (CO 2 ) + R-32 + R-134a, … Show more

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Cited by 3 publications
(1 citation statement)
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“…The optimized AAD obtained with a Helmholtz type EOS was 1.13%, whereas that with REFPROP v9.0 was 3.63%. Akasaka [32] gave an assessment of three thermodynamic models through critical point calculations for ternary and quaternary HFC refrigerant mixtures (including R32) based on Helmholtz energy EOS. The deviations of the critical points are within 1%.…”
Section: Thermophysical Properties Of R32 Blendsmentioning
confidence: 99%
“…The optimized AAD obtained with a Helmholtz type EOS was 1.13%, whereas that with REFPROP v9.0 was 3.63%. Akasaka [32] gave an assessment of three thermodynamic models through critical point calculations for ternary and quaternary HFC refrigerant mixtures (including R32) based on Helmholtz energy EOS. The deviations of the critical points are within 1%.…”
Section: Thermophysical Properties Of R32 Blendsmentioning
confidence: 99%