IntroductionBrown coal is an important natural resource used in Poland and other countries, e.g. Germany, Russia, Turkey, Greece, etc., for power generation. It is an important fossil fuel and is found in several regions of Poland, including the Wielkopolskie, Łódzkie, and Dolnośląskie provinces and there is a potential for brown coal mining in Lubuskie province, [1]. New open-pit mines are going to be opened in Wielkopolska Province, i.e. the Mąkoszyn-Grochowiska mine and possibly in Czempiń, Krzywiń, and Gostyń. Currently, about 35 % of energy production in Poland comes from brown coal and new open-pit mines because of the low price of such a energy production in comparison to other sources. [2]. Due the technology of excavation, openpit mines cause several changes in the environment, such as shifts in landscape structure and changes of local hydrology and hydrogeology, while they also affect air quality, create a cone of depression by drainage, and thus press on surface waters. In the regions mentioned above there exists a potential risk for river water quality related to the presence of heavy metals in mine waters. Two types of lignite mine waters are present, i.e. mine waters from deep-seated drainage with mostly good quality, which may be discharged to rivers without treatment, and surface drainage, which requires treatment in settling reservoirs and sometimes application of chemicals, such as PIX, to increase the rate of coagulation and sedimentation [3,4].Studies on heavy metals covering many environmental issues and interactions have a long history in Poland and Pol. J. Environ. Stud. Vol. 23, No. 6 (2014), 2217-2222 Original Research Results showed that the impact of lignite mine waters on total heavy metals in river sediments was low in the case of the Noteć and Pichna rivers. In Grójecki Channel at the site situated 1 km below the mine waters discharge the total heavy metal concentration in the bottom substrate was significantly higher than above the mine waters discharge outlet. An opposite trend was observed in the Widawka River sediments (715 mg of heavy metals·kg -1 of dry matter), where the total heavy metal concentration in the substrate 1 km below the mine waters discharge outlet decreased by approx. 44%. This was related to low concentrations of heavy metals in the Bełchatów mine waters, amounting to 0.033 mg·L -1 .
Heavy Metals in Waters and