2023
DOI: 10.1016/j.ijhydene.2023.02.049
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An efficient and durable bifunctional electrocatalyst based on PdO and Co2FeO4 for HER and OER

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Cited by 59 publications
(13 citation statements)
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“…Compared to the individual FeCo-S, the positions of the Fe 2p 3/2 and Fe 2p 1/2 peaks have shifted to lower energy by 0.7 and 2.7 eV, respectively. It is indicate that the Co 2p spectrum of FeCo-S-Ni 2 P/NF exhibits six typical peaks at 774.8, 779.8, 785.4, 792.4, 795.7, and 800.2 eV, corresponding to Co 3+ , Co 2+ , satellite peak, Co 3+ , Co 2+ , and satellite peak (Figure c). , Compared to the individual FeCo-S, the positions of the two Co 2+ peaks have shifted to lower energy by 1.4 and 2.0 eV. Notably, characteristic peaks of FeP and CoP were not detected, indicating that the composition of FeCo-S coated on NF did not change during the phosphorization process, further confirming the successful synthesis of the FeCo-S/Ni 2 P/NF heterostructure.…”
Section: Resultsmentioning
confidence: 91%
“…Compared to the individual FeCo-S, the positions of the Fe 2p 3/2 and Fe 2p 1/2 peaks have shifted to lower energy by 0.7 and 2.7 eV, respectively. It is indicate that the Co 2p spectrum of FeCo-S-Ni 2 P/NF exhibits six typical peaks at 774.8, 779.8, 785.4, 792.4, 795.7, and 800.2 eV, corresponding to Co 3+ , Co 2+ , satellite peak, Co 3+ , Co 2+ , and satellite peak (Figure c). , Compared to the individual FeCo-S, the positions of the two Co 2+ peaks have shifted to lower energy by 1.4 and 2.0 eV. Notably, characteristic peaks of FeP and CoP were not detected, indicating that the composition of FeCo-S coated on NF did not change during the phosphorization process, further confirming the successful synthesis of the FeCo-S/Ni 2 P/NF heterostructure.…”
Section: Resultsmentioning
confidence: 91%
“…Figure S7d,f depicts the O 1s photoelectron spectra with high resolution for CuO-400 NEs, CuO-600, and CuO-800. In this spectrum, the oxygen species on the surface of the oxygen carrier are primarily composed of lattice oxygen (O L ), O v , and chemisorbed oxygen (O abs ) with binding energies of 529.23, 530.87, and 534.0 eV, respectively. , XPS is a complex and powerful tool for finding O v in composites Table S3 shows the peak location as well as the relative contents of the O L , O v , and O ads species.…”
Section: Resultsmentioning
confidence: 99%
“…Electrochemical water splitting (EWS) is an exciting new technology, a renewable, safe, and eco-friendly energy source for producing clean fuels such as hydrogen and oxygen gases with zero carbon emission . The fact that EWS comprises two half-reactions: the sluggish four-electron transfer oxygen evolution reaction (OER) and the easy two-electron transfer hydrogen evolution reaction (HER). , OER needs multiphase electron transfer connected to a proton and a significant overpotential to get past the slow kinetics, preventing the water splitting from happening. Additionally, the OER reaction is hampered by two key terminologies: slow kinetics and significant overpotential values. , Investigating an efficient and durable electrocatalyst with high electrocatalytic activity is necessary to address these issues. , …”
Section: Introductionmentioning
confidence: 99%
“…2 The fact that EWS comprises two half-reactions: the sluggish four-electron transfer oxygen evolution reaction (OER) and the easy two-electron transfer hydrogen evolution reaction (HER). 3,4 OER needs multiphase electron transfer connected to a proton and a significant overpotential to get past the slow kinetics, preventing the water splitting from happening. Additionally, the OER reaction is hampered by two key terminologies: slow kinetics and significant overpotential values.…”
Section: ■ Introductionmentioning
confidence: 99%