“…Traditionally, a portion of dithiocarbamates were prepared through the reactions of amines, thiophosgene, isothiocyanate [12] or the combination of amines, carbon monoxide and sulfur [13] . Recently, the three‐component reactions of amines, carbon disulfide, and electrophilic alkenes have been reported by Guo, [14] Saidi, [15] Azizi, [16] Jerome, [17] Li, [18] Veignie [19] and Singh, [20] respectively (Scheme 1, a). However, the well‐known methodologies suffer from some drawbacks, such as foul‐smelling substrates, costly metal catalysts and harsh reaction conditions.…”