“…Ligands L1 a , f , g , L11 a , f , g , L12 g , L14 g and L18 f , g and complexes [Rh(cod)( L14 g )]BF 4 and [Ir(cod)( L14 g )]BAr F were synthesized as previously reported . Substrates S1 , S2 , S5 , S6 – S7 , S8 , S9 , S10 – S11 , S12 – S14 , S17 – S23 , S24 , S25 , S26 , S31 , S33 – S38 , S39 – S43 , S44 – S45 and S46 were prepared following literature procedures. All other reagents are commercially available and were used as received.…”