Gravitational waves and electromagnetic radiations from a neutron star merger were discovered on 17 August 2017. Multiband observations of the optical transient have identified brightness and spectrum features broadly consistent with theoretical predictions. According to the theoretical model, the optical radiation from a neutron star merger originates from the radioactive decay of unstable nuclides freshly synthesized in the merger ejecta. In about a day the ejecta transits from an optically thick state to an optically thin state due to its subrelativistic expansion. Hence, we expect that about a day after the merger, the gamma-ray photons produced by radioactive decays start to escape from the ejecta and make it bright in the MeV band. In this paper, we study the features of the radioactive gamma-ray emission from a neutron star merger, including the brightness and the spectrum, and discuss the observability of the gamma-ray emission. We find that more than 95% of the radiated gamma-ray energy is carried by photons of 0.2-4 MeV, with a spectrum shaped by the nucleosynthesis process and the subrelativistic expansion of the ejecta. Under favorable conditions, a prominent pair annihilation line can be present in the gamma-ray spectrum with the energy flux about 3-5% of the total. For a merger event similar to GW170817, the gamma-ray emission attains a peak luminosity ≈ 2 × 10 41 erg s −1 at ≈ 1.2 day after the merger, and fades by a factor of two in about two days. Such a source will be detectable by Satellite-ETCC if it occurs at a distance 12 Mpc. lifetimes and quantum states, whose decay releases energies in the form of neutrinos, gamma-ray photons, and the kinetic energy of electrons, positrons, and other particles. Because the merger ejecta is initially opaque to photons and particles but transparent to neutrinos, only neutrinos can escape freely and the energies carried by photons and particles will be thermalized and eventually escape from the surface of the ejecta in the form of blackbody radiation. Because of the subrelativistic expansion of the ejecta, all emission and absorption lines from the surface of the ejecta are broadened and merged smoothly. As a result, a smooth and almost featureless thermal spectrum is generated (with superposition of smooth undulations that might arise from broad absorptions, Tanaka et al. 2018), which is verified by the observations of SSS17a/AT2017gfo (Pian et al. 2017). The intense near-infrared emissions have sometimes been used to argue for the presence of lanthanides in the merger-presumably produced by the r-process (rapid neutron capture process) in the merger ejecta-but this is very indirect and not conclusive.The most direct approach for identification of nuclear elements produced during the nucleosynthesis process, and hence the energy mechanism for powering the optical transient from a neutron star merger, would be the direct observation of the gamma-ray photons emitted by the radioactive decay in the merger ejecta. However, this can only be possible after the ej...