Magnetic hydrogel actuators have promising applications
in soft
robots, wastewater treatment, and underwater detection due to the
advantages of their remote control and high magnetic penetration.
However, their controllability is limited by the general fabrication
methods of doping paramagnetic nanoparticles and nonuniform ferromagnetic
nanoparticles with a weak or nonconfigurable magnetic distribution.
Herein, we report a kind of ferromagnetic hydrogel actuator comprising
oriented ferromagnetic Co nanorods with high magnetic anisotropy,
and the magnetic domains can be flexibly programmed by external fields.
To demonstrate the generality of the approach and to research how
the flexibility of the hydrogel hosts influences the behavior of the
actuators, three kinds of hydrogel hosts have been used, including
silica hydrogel, cellulose hydrogel, and clay hydrogel. The silica
hydrogel actuators provide a holistic response. The cellulose hydrogel
actuator can achieve a certain degree of deformation. The clay hydrogel
actuators are capable of achieving large deformations such as the
knot and the bow-knot. Furthermore, biomimetic actuators with the
capacities for wriggling, paddling, and climbing simple obstacles
are designed by utilizing the bending deformations of the clay hydrogel.
In conclusion, this work provides an alternative strategy for designing
and fabricating magnetically actuated hydrogel actuators for imitating
biological units or constructing soft robots by regulating the orientation
and distribution of ferromagnetic nanoparticles.