2009
DOI: 10.1016/j.tetlet.2009.10.064
|View full text |Cite
|
Sign up to set email alerts
|

An electrostatic scale of substituent resonance effect

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4
1

Citation Types

0
43
0

Year Published

2015
2015
2023
2023

Publication Types

Select...
7

Relationship

2
5

Authors

Journals

citations
Cited by 33 publications
(43 citation statements)
references
References 31 publications
0
43
0
Order By: Relevance
“…The 13 C NMR chemical shifts of carbon atoms of 3(a-k) are correlated with Hammett substituent constants and SwainLupton parameters. The following different Hammett substituent constants (r, r I , r R , r R o ) and Swain-Lupton substituent parameters (F, R) data were taken from the literature [44][45][46][47][48][49].…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The 13 C NMR chemical shifts of carbon atoms of 3(a-k) are correlated with Hammett substituent constants and SwainLupton parameters. The following different Hammett substituent constants (r, r I , r R , r R o ) and Swain-Lupton substituent parameters (F, R) data were taken from the literature [44][45][46][47][48][49].…”
Section: Resultsmentioning
confidence: 99%
“…Qualitatively RSE can be understood on the basis of the so-called p-polarization mechanism, first proposed by Reynolds et al [50] and later characterized in a more detailed fashion by Bromilow et al [48,51]. Each p-unit is thought to be polarized separately, the polarization being induced by the substituent dipole in another part of the molecule.…”
Section: Resultsmentioning
confidence: 99%
“…Values of various selected Hammett substituent constants (r, r + , r À , r I, r R , r R o ) using Eqs. (1)-(4) are taken from the literature [55][56][57][58][59][60].…”
Section: Resultsmentioning
confidence: 99%
“…Qualitatively RSE can be understood on the basis of the so-called p-polarization mechanism, first proposed by Reynolds et al [61] and later characterized in a more detailed fashion by Bromilow et al [60,63]. Each p-unit (a double bond, triple bond or aromatic ring system) is thought to be polarized separately, the polarization being induced by the substituent dipole in another part of the molecule.…”
Section: Resultsmentioning
confidence: 99%
“…Further, MESP analysis opens up new ways to classify, quantify, and characterize various types of lone pairs in chemical systems and provides a simple interpretation of chemical reactivity. MESP analysis has already shown its utility in the study of understanding electron localization/delocalization features and also for interpreting a wide range of chemical and biological phenomena …”
Section: Introductionmentioning
confidence: 99%