An empirical analysis of the contributions of intermolecular dispersion interactions to the vaporization enthalpy of nonelectrolytes

Nikolaev, V. F.; Vereshchagin, A. N.; Strobykin, S. I.

doi:10.1007/bf00962457

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Consequences For Materials Selection and Synthesis1

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“…20 -22 The enthalpy itself depends on temperature, and Yaws and Yang 20 have correlated ⌬H v at a temperature T to ⌬H v 1 at the normal boiling point T 1 and to the critical temperature T c by (14) for 700 organic liquids. Perhaps one of the most useful surveys for this purpose is by Nikolaev and coworkers, 21 in which ⌬H v is given by…”

Section: Consequences For Materials Selection and Synthesismentioning

confidence: 99%

Multiparameter mapping of polymer properties for fast thermolysis of powder moldings

Song

Evans

Edirisinghe

et al. 1998

J. Appl. Polym. Sci.

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Ceramic or metal injection molding involves the shaping of a crowded suspension of particles in a polymer that is later removed by thermolysis. During heating, degradation products dissolve in the parent polymer and diffuse to the free surfaces where evaporation occurs. If heated too rapidly in the initial stage, the solution at the center of the molding boils and a bubble forms. This article explores the implications of a multiparameter model that predicts the highest permissible heating rate in terms of polymer properties and maps the outcome. The aim is to develop criteria for the deliberate synthesis of thermally labile copolymers from a knowledge of the desirable property combinations.

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Section: Consequences For Materials Selection and Synthesismentioning

confidence: 99%