The air-based photovoltaic-thermal collector (PVTC) is a system that can generate electricity and heated air simultaneously from solar energy. This study investigates the electrical and thermal performances of an air-based single-pass double-flow photovoltaic-thermal collector (SPDFPVTC) coupled with a nonuniform cross-section rib (NUCSR) under various operating conditions. The rib is installed at the rear of the photovoltaic panel to enhance the heat transfer performance between the photovoltaic panel and the flowing air. Based on the energy balance equations, a mathematical model of the proposed SPDFPVTC is established and validated by experimental results. The solar intensity, air mass flow rate, and wind speed are selected as operating conditions. The effects of these operating conditions on the electrical and thermal performance of the SPDFPVTC have been discussed. In addition, this study evaluates the daily performance of SPDFPVTC with and without NUCSR. The average electrical, thermal, and overall efficiency were 17.59%, 43.96%, and 61.55%, respectively, for SPDFPVTC with NUCSR and 16.97%, 38.87%, and 55.83%, respectively, for SPDFPVTC without NUCSR. Consequently, installing NUCSR could enhance the daily electrical, thermal, and overall energy output of SPDFPVTC by 4.33%, 13.23%, and 10.63%, respectively.