On an almost Hermitian manifold, we have two Hermitian scalar curvatures with respect to any canonical Hermitian connection defined by P. Gauduchon. Explicit formulas of these two Hermitian scalar curvatures are obtained in terms of Riemannian scalar curvature, norms of decompositions of covariant derivative of the fundamental 2-form with respect to the Levi-Civita connection, and the codifferential of the Lee form. Then we get some inequalities of various total scalar curvatures and some characterization results of the Kähler metric, balanced metric, locally conformally Kähler metric and the k-Gauduchon metric. As corollaries, we show some results related to a problem given by Lejmi-Upmeier [27] and a conjecture given by Angella-Otal-Ugarte-Villacampa [2].