Inhibiting the Leidenfrost effect has drawn extensive
attention
due to its detrimental impact on heat dissipation in high-temperature
industrial applications. Although hierarchical structures have improved
the Leidenfrost point to over 1000 °C, the current performance
of single-scale structures remains inadequate. Herein, we present
a facile high-temperature treatment method to fabricate superhydrophilic
nickel foams that demonstrate ultrafast droplet permeation within
tens of milliseconds, elevating the Leidenfrost point above 500 °C.
Theoretical analysis based on the pressure balance suggests that these
remarkable features arise from the superhydrophilic property, high
porosity, and large pore diameter of nickel foams that promote capillary
wicking and vapor evacuation. Compared to solid nickel surfaces with
a Leidenfrost temperature of approximately 235 °C, nickel foams
nucleate boiling at high superheat, triggering an order of magnitude
higher heat flux. The effects of the pore diameter and surface temperature
on droplet permeation behaviors and heat transfer characteristics
are also elucidated. The results indicate that droplet permeation
is dominated by inertial and capillary forces at low and high superheat,
respectively, and moderate pore diameters are more conducive to facilitating
droplet permeation. Furthermore, our heat transfer model reveals that
pore diameter plays a negligible role in the heat flux at high surface
temperatures due to the trade-off between effective thermal conductivity
and specific surface area. This work provides a new strategy to address
the Leidenfrost effect by metal foams, which may promise great potential
in steel forging and nuclear reactor safety.