An experimental investigation of droplets impinging vertically on a deep liquid pool of the same fluid was conducted. Coalescence and jetting as two of the main regimes were identified and studied. Five fluids, distilled water, technical ethanol, n-pentane, methanol and 1-propanol were used for providing different liquid-phase physical properties with density from 600 to 1,000 kg/m 3 , viscosity from 0.20 to 2.00 mPa s, and surface tension from 13.7 to 72.0 mN/m. Except for the experimental run of n-pentane, which was carried out in n-pentane saturated vapor, the ambient gas for the other experiments was air. The impact processes of micro-level (diameter below 1 mm) droplets were captured using a high-speed camera with a backlight. The observations, velocity and diameter ranges of the experimental runs were described, and based on them, the effects of the liquid-phase properties were studied. It was found that both low viscosity and low surface tension can increase the instability during impact processes. By curve-fitting, the transition from coalescence to jetting was characterized by using two models, one employing the Weber number (We) and the Ohnesorge number (Oh), and one employing the Froude number (Fr) and the Capillary number (Ca). Both models characterize the coalescence-jetting threshold well. The We-Oh model was based on a commonly used model from Cossali et al. (in Exp Fluids 22:463-472, 1997) for characterizing coalescence-splashing. For the small droplet diameters (below 1 mm) considered in this study, it was required to modify the We-Oh model with a diameter-dependent term to fit the sharp change in thresholds for fluids with relatively high viscosity. The Fr-Ca model has not previously been presented in the literature. A comparison of the two models with literature data (Rodriguez and Mesler, J Colloid Interface Sci 106(2): [347][348][349][350][351][352] 1985) indicates that they are also valid for impacts of droplets with diameters above 1mm. Calculation methods to generalize the two models were proposed.