Understanding the mechanical properties of coal is crucial for efficient mining and disaster prevention in coal mines. Coal contains numerous cracks and fissures, resulting in low strength and challenges in preparing standard samples for testing coal fracture toughness. In engineering, indicators such as the hardness coefficient (f value) and Hardgrove grindability index (HGI) are straightforward to measure. Various experiments, including drop weight, grinding, uniaxial compressive strength and three-point bending experiments, were conducted using notched semi-circular bend (NSCB) specimens and particle sizes of 1–2 mm/0.425–1 mm. Theoretical and experimental results indicate that the hardness coefficient of coal and rock is proportional to the crushing work ratio and inversely proportional to the mean equivalent diameter. Moreover, the square of the fracture toughness of coal and rock is directly proportional to the crushing work ratio, inversely proportional to the newly added area, directly proportional to the mean equivalent diameter and directly proportional to the hardness coefficient. The Mode-I fracture toughness of coal and rock can be rapidly determined through the density, the equivalent diameter after crushing and the elastic modulus, with experimental verification of its accuracy. Considering that smaller particle sizes exhibit greater resistance to breakage, the distribution mode of new surface areas after particle breakage was established, influenced by the initial particle size and the energy of a single broken particle. This study can assist in quickly and accurately determining the fracture toughness of coal.