“…In these models, the liquid contact angle (h, often measured in the macroscale) and the characteristic Kelvin length (k K = cV m /R g T where c and V m are the liquid surface tension and molar volume, respectively; R g = 8.314 J/mol K; T = temperature; k K = typically in the range of 0.5-1.5 nm) are two key parameters controlling the size of the liquid meniscus and the magnitude of the capillary force at a given contact geometry and relative partial pressure of the vapor (p/p sat ). Various elegant models have been developed to take into account the effects of solid surface roughness, liquid condensation, and evaporation kinetics [1,2,4,6,9,14,19,20].…”