Articles you may be interested inAn algorithm for nonrelativistic quantum-mechanical finite-nuclear-mass variational calculations of nitrogen atom in L = 0, M = 0 states using all-electrons explicitly correlated Gaussian basis functions An algorithm for quantum mechanical finite-nuclear-mass variational calculations of atoms with L = 3 using allelectron explicitly correlated Gaussian basis functions J. Chem. Phys. 138, 104107 (2013); 10.1063/1.4794192 Molecular structure calculations: A unified quantum mechanical description of electrons and nuclei using explicitly correlated Gaussian functions and the global vector representation Electron affinity of Li 7 calculated with the inclusion of nuclear motion and relativistic corrections Nonadiabatic variational calculations for the anion ground state energies, mass shifts, and electron affinities of Hydrogen, Deuterium and Tritium are reported. Electron affinities values are 6083.0994, 6086.7137, and 6087.9168 cm Ϫ1 for Hydrogen, Deuterium, and Tritium, respectively. These results were obtained using a basis of explicitly correlated Gaussians. Exact nonrelativistic energy bounds are carefully predicted: E(H Ϫ )ϭϪ0.5 274 458 811, E(D Ϫ )ϭϪ0.5 275 983 247, and E(T Ϫ )ϭϪ0.5 276 490 482 in hartree energy units. It is shown that these new bounds cannot be obtained using the infinite nuclear mass approximation plus Rydberg scaling and the usual first order mass polarization correction.