Biodegradable polylactic acid (PLA) nanofibrous membranes
(NFMs)
hold great potential to address the increasing airborne particulate
matter (PM) and dramatic accumulation of plastic/microplastic pollution.
However, the field of PLA NFM-based filters is still in its infancy,
frequently dwarfed by the bottlenecks regarding relatively low surface
activity, poor electroactivity, and insufficient PM capturing mechanisms.
This effort discloses a microwave-assisted approach to minute-level
synthesis of dielectric ZIF-8 nanocrystals with high specific surface
area (over 1012 m2/g) and ultrasmall size (∼240
nm), which were intimately anchored onto PLA nanofibers (PLA@ZIF-8)
by a combined “electrospinning–electrospray”
strategy. This endowed the PLA@ZIF-8 NFMs with largely increased electroactivity
in terms of elevated dielectric coefficient (an increase of 202%),
surface potential (up to 5.8 kV), and triboelectric properties (output
voltage of 30.8 V at 10 N, 0.5 Hz). Given the profound control over
morphology and electroactivity, the PLA@ZIF-8 NFMs exhibited efficient
filtration of PM0.3 (97.1%, 85 L/min) with a decreased
air resistance (592.5 Pa), surpassing that of the pure PLA counterpart
(88.4%, 650.9 Pa). This was essentially ascribed to realization of
multiple filtration mechanisms for PLA@ZIF-8 NFMs, including enhanced
physical interception, polar interactions, and electrostatic adsorption,
and the unique self-charging function triggered by airflow vibrations.
Moreover, perfect antibacterial performance was achieved for PLA@ZIF-8,
showing ultrahigh inhibition rates of 99.9 and 100% against E. coli and S. aureus, respectively. The proposed hierarchical structuring strategy, offering
the multifunction integration unattainable with conventional methods,
may facilitate the development of biodegradable long-term air filters.