Quenching of electronically excited nitrogen state, ( )can be explained by quenching by electrons. Long-lived plasma at time scale of hundreds nanoseconds after the end of the pulse is observed. High electron densities, about 10 14 cm −3 at 27 mbar, are sustained by reactions of associative ionization. Kinetic 1D numerical modeling and comparison of calculated results with experimentally measured electric fields in the second high-voltage pulse 250 ns after the initial pulse, and electron density measurements in the afterglow confirm the validity of the suggested mechanism.