An interdigitated 3D framework with 5-connected BN topology

Wang, Cun-Kuan; Zhou, Yan; Xu, Liping; Han, Lei

doi:10.1016/j.inoche.2011.04.019

Cited by 5 publications

(1 citation statement)

References 29 publications

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“…This results in the uncoordinated imidazole and pyridyl groups which direct the formation of 3D interdigitated structure (Figure ). In addition, a series of 2D MOFs based on different metal centers (M = Mn, Zn, Co, and Cd) and tetracyanoquinodimethane dianion (TCNQ 2– ) in the presence of pyridine-based co-ligands such as pyridine, 4-methylpyridine, quinoline, and 4-phenylpyridine also afforded 2D to 3D interdigitated structures. , Additionally, several 2D MOFs with corrugated layers were also noted to exhibit interdigitated 3D architectures. − …”

Section: Different Entanglementsmentioning

confidence: 88%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties and applications, including gas and guest sorption, storage and separation of gases and small molecules, catalysis, luminescence, sensing, magnetism, and energy storage and conversion. Among MOFs, two-dimensional (2D) compounds are also known as 2D CPs or 2D MOFs. Since the discovery of graphene in 2004, 2D materials have also been widely studied. Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements. This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.

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